1-Chloro-1,1,2,3,3,3-hexafluoropropane

Base Information

• Chemical Name: 1-Chloro-1,1,2,3,3,3-hexafluoropropane
• CAS No.: 359-58-0
• Molecular Formula: C3HClF6
• Molecular Weight: 186.484
• Hs Code.: 2903791090
• DSSTox Substance ID: DTXSID10957319
• Nikkaji Number: J1.048.960A
• Mol file: 359-58-0.mol

Synonyms:1-Chloro-1,1,2,3,3,3-hexafluoropropane;359-58-0;HCFC-226ea;SCHEMBL404187;DTXSID10957319;JODPGPKOJGDHSV-UHFFFAOYSA-N;MFCD04038865;AKOS006228039;1,1,1,2,3,3-hexafluoro-3-chloropropane;A823060;1-chloranyl-1,1,2,3,3,3-hexakis(fluoranyl)propane

Chemical Property of 1-Chloro-1,1,2,3,3,3-hexafluoropropane

Chemical Property:

• Vapor Pressure: 943mmHg at 25°C
• Refractive Index: 1.282
• Boiling Point: 18.9 °C at 760 mmHg
• PSA: 0.00000
• Density: 1.521 g/cm³
• LogP: 2.71840
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 1
• Exact Mass: 185.9670967
• Heavy Atom Count: 10
• Complexity: 117

Purity/Quality:

98%min ^*data from raw suppliers

1-CHLORO-1,1,2,3,3,3-HEXAFLUOROPROPANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(F)(F)F)(C(F)(F)Cl)F

Technology Process of 1-Chloro-1,1,2,3,3,3-hexafluoropropane

There total 8 articles about 1-Chloro-1,1,2,3,3,3-hexafluoropropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.5%

1,1-dichloroethane (75-34-3) + perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) → 1-chloro-1,1,2,3,3,3-hexafluoro-propane (359-58-0) + CF3CClFCHF2 (51346-64-6) + 1,4-Dichloro-1,1,2-trifluoro-2-trifluoromethyl-butane + 2,5-Dichloro-1,1,1,2,3,3-hexafluoro-pentane

Guidance literature:

at 290 ℃; for 96h;

DOI:10.1016/S0022-1139(00)81246-4

Reference yield: 30.0%

perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) + 1,1,1-trichloroethane (71-55-6,74552-83-3) → 1-chloro-1,1,2,3,3,3-hexafluoro-propane (359-58-0) + CF3CClFCHF2 (51346-64-6) + 1,1-Dichloro-2,3,3-trifluoro-2-trifluoromethyl-cyclobutane + (E)-1,4-Dichloro-3,4,4-trifluoro-3-trifluoromethyl-but-1-ene

Guidance literature:

at 290 ℃; for 96h; Further byproducts given;

DOI:10.1016/S0022-1139(00)81246-4

Reference yield:

2,2-dichloro-1,1,1,3,3,3-hexafluoro-propane (1652-80-8) + 1,2-dichlorohexafluoropropane (661-97-2) → 1,1,1,2,3,3,3-Heptafluoropropane (431-89-0) + perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) + 1,1,1,2,2,3-hexafluoropropane (677-56-5) + 1,1,1,2,3,3-hexafluoropropane (431-63-0) + 1,1,1,3,3,3-hexafluoropropane (690-39-1) + 2-chloro-1,1,1,3,3,3-hexafluoropropane (431-87-8,134308-72-8) + 1,1,1,2-tetrafluoropropane (421-48-7) + 1-chloro-1,1,2,3,3,3-hexafluoro-propane (359-58-0) + 1,1,1,2,2-pentafluoropropane (1814-88-6) + CF3CClFCHF2 (51346-64-6)

Guidance literature:

With hydrogen fluoride; 1percent Pd supported on fluorided alumina catalyst; at 125 - 300 ℃; for 0.00833333h; under 760.051 Torr; Product distribution / selectivity; Gas phase;

upstream raw materials:

1,1-dichloroethane

perfluoropropylene

1,1,1-trichloroethane

1,2-dichlorohexafluoropropane

Refernces

• 1、 -. "1,2,3,3,3-PENTAFLUOROPROPENE PRODUCTION PROCESSES". Page/Page column 14. . Retrieved 2008/06/13.
• 2、 -. "Functionalized Copolymers of Terminally Functionalized Perfluoro (Alkyl Vinyl Ether) Reactor Wall for Photochemical Reactions, Process for Increasing Fluorine Content in Hydrocaebons and Halohydrocarbons and Olefin Production". Page/Page column 5. . Retrieved 2008/06/13.