(Z)-beta-Methoxy-alpha-methylstyrene

Base Information

Chemical Name:(Z)-beta-Methoxy-alpha-methylstyrene
CAS No.:58966-08-8
Molecular Formula:C10H12 O
Molecular Weight:148.205
Hs Code.:
European Community (EC) Number:261-527-1
DSSTox Substance ID:DTXSID901279144
Nikkaji Number:J2.214.069H,J308.578C
Mol file:58966-08-8.mol

Synonyms:58966-08-8;EINECS 261-527-1;(Z)-beta-Methoxy-alpha-methylstyrene;1-Methoxy-2-phenyl-1-propene;DTXSID901279144;[(Z)-2-Methoxy-1-methylethenyl]benzene;[(1Z)-2-Methoxy-1-methylethenyl]benzene

Suppliers and Price of (Z)-beta-Methoxy-alpha-methylstyrene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of (Z)-beta-Methoxy-alpha-methylstyrene

Chemical Property:

Boiling Point:215.7oC at 760 mmHg
Flash Point:69.4oC
PSA：9.23000
Density:0.946g/cm3
LogP:2.69380
XLogP3:2.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:148.088815002
Heavy Atom Count:11
Complexity:132

Purity/Quality:: 98%Min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=COC)C1=CC=CC=C1
Isomeric SMILES:C/C(=C/OC)/C1=CC=CC=C1

Technology Process of (Z)-beta-Methoxy-alpha-methylstyrene

There total 5 articles about (Z)-beta-Methoxy-alpha-methylstyrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 591-50-4
iodobenzene

: 13169-00-1
Methoxyallene

: 19149-98-5
(3-methoxyprop-1-en-2-yl)benzene

: 58966-08-8
(Z)-(1-methoxyprop-1-en-2-yl)benzene

: 58966-09-9
(E)-(1-methoxyprop-1-en-2-yl)benzene

Guidance literature:: Methoxyallene; In tetrahydrofuran; at 20 ℃; for 12h;

iodobenzene; With tetrabutyl ammonium fluoride; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In tetrahydrofuran; chloroform; at 65 ℃; for 24h; Further stages. Title compound not separated from byproducts.;
DOI:10.1039/b712998j

Reference yield:

: 67-56-1
methanol

: 98-83-9,6144-04-3,25014-31-7,42612-14-6
isopropenylbenzene

: 58966-08-8
(Z)-(1-methoxyprop-1-en-2-yl)benzene

: 58966-09-9
(E)-(1-methoxyprop-1-en-2-yl)benzene

Guidance literature:: With chloropyridinecobaloxime(III); 9-(2-mesityl)-10-methylacridinium perchlorate; In acetonitrile; at 20 ℃; for 12h; Overall yield = 69 %; Overall yield = 20.4 mg; Irradiation; Inert atmosphere; Schlenk technique;
DOI:10.1002/anie.201609274

Reference yield:

: 4009-98-7
(methoxymethyl)triphenylphosphonium chloride

: 98-86-2
acetophenone

: 58966-08-8
(Z)-(1-methoxyprop-1-en-2-yl)benzene

: 58966-09-9
(E)-(1-methoxyprop-1-en-2-yl)benzene

Guidance literature:: (methoxymethyl)triphenylphosphonium chloride; With potassium tert-butylate; In tetrahydrofuran; at 0 - 10 ℃; for 1h;

acetophenone; In tetrahydrofuran; for 4h; Overall yield = 88 percent; Overall yield = 2.61 g;
DOI:10.1021/acs.joc.0c02987