dimethyl hexane-1,6-diylbiscarbamate

Base Information

• Chemical Name: dimethyl hexane-1,6-diylbiscarbamate
• CAS No.: 6030-54-2
• Molecular Formula: C10H20N2O4
• Molecular Weight: 232.28
• Mol file: 6030-54-2.mol

Synonyms:

Chemical Property of dimethyl hexane-1,6-diylbiscarbamate

Chemical Property:

• Vapor Pressure: 4.63E-06mmHg at 25°C
• Boiling Point: 382.7°C at 760 mmHg
• Flash Point: 185.3°C
• Density: 1.064g/cm³

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of dimethyl hexane-1,6-diylbiscarbamate

There total 3 articles about dimethyl hexane-1,6-diylbiscarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

methanol (67-56-1) + N,N'-hexanediyl bis-(thiocarbamic acid (S-phenyl) ester) (61578-93-6) → 1,6-bis(methoxycarbonylamino)hexane (6030-54-2) + diphenyldisulfane (882-33-7)

Guidance literature:

With triethylamine; for 20h; Reflux;

DOI:10.1021/acs.orglett.6b01023

Reference yield:

hexamethylene bisacetamide (3073-59-4) + carbonic acid dimethyl ester (616-38-6) → 1,6-bis(methoxycarbonylamino)hexane (6030-54-2) + methyl 1,6-hexamethylenemonocarbamate monoacetamide (1206701-19-0)

Guidance literature:

magnesium oxide; zinc trifluoromethanesulfonate; at 180 ℃; for 2h; Product distribution / selectivity;

Reference yield:

methanol (67-56-1) + 1,6-Hexanediamine (124-09-4) + carbon monoxide (201230-82-2) → hexanediyldiformamide (35161-65-0) + 1,6-bis(methoxycarbonylamino)hexane (6030-54-2)

Guidance literature:

With oxygen; triphenylphosphine; bis(triphenylphosphine)gold(I) chloride; at 200 ℃; for 3h; under 37503.8 Torr;

DOI:10.1039/b009575n

upstream raw materials:

methanol

1,6-Hexanediamine

carbon monoxide

hexamethylene bisacetamide

Downstream raw materials:

N,N'-dinitroso-N,N'-hexanediyl-bis-carbamic acid dimethyl ester

Hexamethylene diisocyanate

1-isocyanato-6-methoxycarbonylaminohexane

1,1,6,6-tetramethoxyhexane

Refernces

• 1、 -. "METHOD FOR PRODUCING CARBAMATE COMPOUND". Page/Page column 15. . Retrieved 2011/06/24.