Dibenzyl(diphenyl)phosphanium;bromide

Base Information

Chemical Name:Dibenzyl(diphenyl)phosphanium;bromide
CAS No.:77382-18-4
Molecular Formula:C26H24P+
Molecular Weight:447.354
Hs Code.:
NSC Number:132583

Synonyms:77382-18-4;SCHEMBL5087115;NSC132583;NSC-132583

Suppliers and Price of Dibenzyl(diphenyl)phosphanium;bromide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Dibenzyl(diphenyl)phosphanium;bromide

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
Density:g/cm³
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:6
Exact Mass:446.07990
Heavy Atom Count:28
Complexity:366

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)C[P+](CC2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.[Br-]

Technology Process of Dibenzyl(diphenyl)phosphanium;bromide

There total 12 articles about Dibenzyl(diphenyl)phosphanium;bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 2857-97-8
trimethylsilyl bromide

: 53772-44-4
benzyloxydiphenylphosphine

: 18789-78-1
(Diphenylphosphinyloxy)trimethylsilan

: 77382-18-4
dibenzyl diphenyl phosphonium bromide

Guidance literature:: at 80 ℃; Inert atmosphere;
DOI:10.1002/chem.200800435

Reference yield:

: 100-39-0
benzyl bromide

: 829-85-6
diphenylphosphane

: 77382-18-4
dibenzyl diphenyl phosphonium bromide

: 7650-91-1
benzyldiphenylphosphane

Guidance literature:: With sodium trimethylsilanolate; In dichloromethane-d2; at 20 ℃; for 0.25h; Inert atmosphere;
DOI:10.1021/ic100816u

Reference yield:

: 100-51-6,185532-71-2
benzyl alcohol

: 77382-18-4
dibenzyl diphenyl phosphonium bromide

Guidance literature:: Multi-step reaction with 3 steps

1: tetra-(n-butyl)ammonium iodide / neat (no solvent) / 24 h / 85 °C / Inert atmosphere; Schlenk technique; Sealed tube; Green chemistry

2: Triethoxysilane; titanium(IV) isopropylate / tetrahydrofuran / 1 h / 80 °C / Inert atmosphere; Schlenk technique; Sealed tube

3: tetrahydrofuran / 1 h / 80 °C / Inert atmosphere; Schlenk technique; Sealed tube

With titanium(IV) isopropylate; Triethoxysilane; tetra-(n-butyl)ammonium iodide; In tetrahydrofuran; 1: |Michaelis-Arbuzov Synthesis;
DOI:10.1039/c8gc00931g