Methyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate

Base Information

Chemical Name:Methyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate
CAS No.:41088-52-2
Molecular Formula:C8H12O3
Molecular Weight:156.181
Hs Code.:2932999099
DSSTox Substance ID:DTXSID00884680
Nikkaji Number:J695.211I
Wikidata:Q19694319
Wikipedia:3,4-Epoxycyclohexanecarboxylate_methyl_ester
Mol file:41088-52-2.mol

Synonyms:41088-52-2;Methyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate;methyl 3,4-epoxycyclohexane carboxylate;3,4-Epoxycyclohexane carboxylic acid, methyl ester;MFCD13185927;7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, methyl ester;3,4-epoxycyclohexanecarboxylate methyl ester;7-Oxabicyclo(4.1.0)heptane-3-carboxylic acid, methyl ester;SCHEMBL668029;DTXSID00884680;QCGKUFZYSPBMAY-UHFFFAOYSA-N;7-OXABICYCLO[4.1.0]HEPTANE-3-CARBOXYLIC ACID METHYL ESTER;Methyl 3,4-Epoxycyclohexanecarbonate;AKOS015901832;methyl 3,4-epoxycyclohexanecarboxylate;DS-4341;SY116328;methyl-3',4'-epoxycyclohexane carboxylate;CS-0150729;FT-0686461;EN300-313806;Methyl7-oxabicyclo[4.1.0]heptane-3-carboxylate;3,4-Epoxycyclohexane carboxylic acid,methyl ester;A873147;methyl 7-oxabicyclo[4.1.0]heptane-4-carboxylate;Q19694319;Z1255374199

Suppliers and Price of Methyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
Methyl7-oxabicyclo[4.1.0]heptane-3-carboxylate 95+%
1g
$ 411.00

Chemenu
Methyl7-oxabicyclo[4.1.0]heptane-3-carboxylate 95%
1g
$ 393.00

American Custom Chemicals Corporation
METHYL-7-OXABICYCLO-[4.1.0]-HEPTANE-3-CARBOXYLATE 95.00%
5MG
$ 498.95

Alichem
Methyl7-oxabicyclo[4.1.0]heptane-3-carboxylate
1g
$ 664.00

Alichem
Methyl7-oxabicyclo[4.1.0]heptane-3-carboxylate
250mg
$ 292.60

Total 67 raw suppliers

Chemical Property of Methyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate

Chemical Property:

Vapor Pressure:0.188mmHg at 25°C
Refractive Index:1.484
Boiling Point:210.856 °C at 760 mmHg
Flash Point:79.776 °C
PSA：38.83000
Density:1.167 g/cm³
LogP:0.72690
Storage Temp.:2-8°C
Solubility.:Acetone (Slightly), Chloroform (Slightly), Methanol (Slightly)
XLogP3:0.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:156.078644241
Heavy Atom Count:11
Complexity:178

Purity/Quality:

≥99% ^*data from raw suppliers

Methyl7-oxabicyclo[4.1.0]heptane-3-carboxylate 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1CCC2C(C1)O2
Uses 3,4-Epoxycyclohexanecarboxylate Methyl Ester is a useful reagent for organic synthesis.

Technology Process of Methyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate

There total 3 articles about Methyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 62704-89-6
Methoxy-(3,4-epoxycyclohexyl)-methyl-tert.-butyl-peroxid

: 558-30-5
2-methyl-1,2-epoxypropane

: 41088-52-2
methyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate

: 107-31-3
Methyl formate

: 286-20-4
cyclohexane-1,2-epoxide

: 67-64-1
acetone

: 75-65-0
tert-butyl alcohol

Guidance literature:: In solid matrix; at -196 ℃; for 10h; Rate constant; Thermodynamic data; Irradiation; activation energy;

Reference yield:

: 3685-22-1,3685-26-5,17419-81-7
4-hydroxycyclohexanecarboxylic acid

: 41088-52-2
methyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: 91.1 percent / diethyl ether / 25 °C

2: 2.0 g / pyridine / benzene / 24 h / 25 °C

3: 62.3 percent / 1,8-dizazabicyclo<5.4.0>undec-7-ene (DBU) / dioxane / 1 h / Heating

4: 63 percent / m-chloroperbenzoic acid (MCPBA) / CH₂Cl₂ / 2 h / 0 °C

With pyridine; 1,8-diazabicyclo[5.4.0]undec-7-ene; 3-chloro-benzenecarboperoxoic acid; In 1,4-dioxane; diethyl ether; dichloromethane; benzene;
DOI:10.1021/jo00362a012

Reference yield:

: 636-82-8
cyclohexene-1-carboxylic acid

: 41088-52-2
methyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydrogencarbonate; potassium iodide / dichloromethane / 0.17 h

1.2: 2 h / 20 °C

2.1: 0.17 h / 20 °C

2.2: 3 h

With sodium hydrogencarbonate; potassium iodide; In dichloromethane;