tert-Butyl methacrylate

Base Information

Chemical Name:tert-Butyl methacrylate
CAS No.:585-07-9
Molecular Formula:C8H14O2
Molecular Weight:142.198
Hs Code.:29161400
European Community (EC) Number:209-548-7
NSC Number:20957
UN Number:1993
UNII:F9029V5818
DSSTox Substance ID:DTXSID3060405
Nikkaji Number:J47.811C
Wikidata:Q27277818
Mol file:585-07-9.mol

Synonyms:Methacrylicacid, tert-butyl ester (6CI,7CI,8CI);1,1-Dimethylethyl methacrylate;AcryesterTB;Acryester TBMA;Light Ester TB;NSC 20957;tert-Butyl 2-methylacrylate;tert-Butyl 2-methylpropenoate;tert-Butyl alcohol methacrylate;tert-Butylmethacrylate;tert-Butyl a-methacrylate;

Suppliers and Price of tert-Butyl methacrylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
tert-Butyl methacrylate
50mg
$ 75.00

TCI Chemical
tert-Butyl Methacrylate Monomer (stabilized with MEHQ) >98.0%(GC)
500mL
$ 103.00

TCI Chemical
tert-Butyl Methacrylate Monomer (stabilized with MEHQ) >98.0%(GC)
25mL
$ 29.00

Sigma-Aldrich
tert-Butyl methacrylate 98%, contains 200 ppm monomethyl ether hydroquinone as inhibitor
100ml
$ 68.60

Sigma-Aldrich
tert-Butyl methacrylate 98%, contains 200 ppm monomethyl ether hydroquinone as inhibitor
250ml
$ 138.00

Arctom
tert-Butyl methacrylate 98%
25g
$ 9.00

AK Scientific
tert-Butylmethacrylate,stabilizedwithMEHQ
5mL
$ 10.00

Total 88 raw suppliers

Chemical Property of tert-Butyl methacrylate

Chemical Property:

Appearance/Colour:colorless liquid with an ester like odor
Vapor Pressure:2.82mmHg at 25°C
Melting Point:-60 °C
Refractive Index:n20/D 1.415(lit.)
Boiling Point:156.9 °C at 760 mmHg
Flash Point:41.1 °C
PSA：26.30000
Density:0.875 g/cm³
LogP:1.90420
Storage Temp.:2-8°C
Solubility.:Insoluble in water
Water Solubility.:464mg/L at 20℃
XLogP3:2.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:142.099379685
Heavy Atom Count:10
Complexity:151
Transport DOT Label:Flammable Liquid

Purity/Quality:

98.00% ^*data from raw suppliers

tert-Butyl methacrylate ^*data from reagent suppliers

Safty Information:

Pictogram(s): R10:;
Hazard Codes:Xi
Statements: 10-38
Safety Statements: 16

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CC(=C)C(=O)OC(C)(C)C
Uses tert-Butyl methacrylate (tert-BMA) can be used in the formation of homo and block copolymers by atom transfer radical polymerization (ATRP) for potential usage in coatings, biomaterials and flocculants.

Technology Process of tert-Butyl methacrylate

There total 15 articles about tert-Butyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.2%

: 23877-12-5
tert-butyl bromoisobutyrate

: 67828-69-7
methyl 5-chloro-2,4-dihydroxybenzoate

: 1003567-14-3
4-(1-tert-butoxycarbonyl-1-methylethoxy)-5-chloro-2-hydroxybenzoic acid methyl ester

: 585-07-9,25189-00-8
tert-Butyl methacrylate

Guidance literature:: tert-butyl bromoisobutyrate; methyl 5-chloro-2,4-dihydroxybenzoate; With tetrabutylammomium bromide; potassium carbonate; In 1-methyl-pyrrolidin-2-one; at 60 - 65 ℃; for 16h;

With hydrogenchloride; In 1-methyl-pyrrolidin-2-one; water; pH=~ 4;

Reference yield: 68.99%

: 585-07-9,25189-00-8
tert-Butyl methacrylate

Guidance literature:: With titanium catalyst; at 115 ℃; for 1h;

Reference yield:

: 78-85-3,25120-30-3
2-methylpropenal

: 75-65-0
tert-butyl alcohol

: 585-07-9,25189-00-8
tert-Butyl methacrylate

Guidance literature:: 2-methylpropenal; With tert-butylhypochlorite; In tetrachloromethane; at 20 - 50 ℃; for 5.5 - 6.5h;

tert-butyl alcohol; With triethylamine; In tetrachloromethane; at 0 - 20 ℃; for 19.5h;