Dysprosium(iii)chloride

Base Information

• Chemical Name: Dysprosium(iii)chloride
• CAS No.: 10025-74-8
• Molecular Formula: Cl3Dy
• Molecular Weight: 268.859
• UNII: Q2A03W637H
• DSSTox Substance ID: DTXSID8041909
• Nikkaji Number: J95.977D
• Mol file: 10025-74-8.mol

Synonyms:DTXSID8041909;Dysprosium(iii)chloride;DTXCID6021909;BOXVSFHSLKQLNZ-UHFFFAOYSA-K;AMY22269;Tox21_300819;AKOS024256091;NCGC00254723-01;CAS-10025-74-8

Chemical Property of Dysprosium(iii)chloride

Chemical Property:

• Appearance/Colour: white pwdr.
• Vapor Pressure: 33900mmHg at 25°C
• Melting Point: 680 °C(lit.)
• Boiling Point: 1500°C
• Flash Point: °C
• PSA: 0.00000
• Density: 3.67 g/mL at 25 °C(lit.)
• LogP: 2.06850
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 268.835739
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Dy+3]

Technology Process of Dysprosium(iii)chloride

There total 17 articles about Dysprosium(iii)chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[Dy(chloride)2(water)6]Cl → dysprosium(III) trichloride (10025-74-8)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O; Schlenk techniques; heating Dy compd. under vacuum (1E-3 Torr);

DOI:10.1016/j.poly.2010.02.027

Reference yield:

dysprosium((III) oxide → dysprosium(III) trichloride (10025-74-8)

Guidance literature:

In not given;

DOI:10.1007/s10973-006-7734-8 DOI:10.1007/s10973-008-9203-z

Reference yield:

dysprosium((III) oxide + aluminium trichloride (7446-70-0) → dysprosium(III) trichloride (10025-74-8)

Guidance literature:

In neat (no solvent); absence of moisture; large excess AlCl3, evacuated quartz tube, 573 K; fractional sublimation over 450 to 650 K gradient, removal of residual AlCl3 on heating in Cl2/N2 stream;

upstream raw materials:

aluminium trichloride

tetrachloromethane

hydrogenchloride

chlorine

Downstream raw materials:

[(phenylthioacetate)3Dy(III)(H₂O)]

{Dy(thiophene-2-glyoxal-p-dimethylaminoanil)2Cl₂}Cl

Refernces

• 1、 Ambrozini, B.,Dametto, P. R.,Ionashiro, M.. "Synthesis, characterization and thermal behaviour of solid-state tartrates of heavy trivalent lanthanides and yttrium(III)". . p. 867 - 871. Retrieved 2011.
• 2、 Siqueira,De Carvalho,Rodrigues,Ionashiro,Bannach,Ionashiro. "Synthesis, characterization and thermal behaviour of heavy lanthanide and yttrium pyruvates in the solid state". . p. 95 - 100. Retrieved 2010.
• 3、 Palinkas, Zoltan,Roca-Sabio, Adrian,Mato-lglesias, Marta,Esteban-Gomez, David,Platas-Iglesias, Carlos,De Blas, Andres,Rodriguez-Blas, Teresa,Toth, Eva. "Stability, water exchange, and anion binding studies on lanthanide(III) complexes with a macrocyclic ligand based on 1.7-diaza-12-crown-4: Extremely fast water exchange on the Gd3+ complex". . p. 8878 - 8889. Retrieved 2009.
• 4、 Tolmach,Gorbunov,Gavrichev,Iorish. "Thermodynamic properties of some lanthanide chlorides". . p. 845 - 849. Retrieved 1988.
• 5、 Rodrigues, Emanuel C.,Siqueira, Adriano B.,Ionashiro, Elias Y.,Bannach, Gilbert,Ionashiro, Massao. "Synthesis, characterization and thermal behaviour of solid 4-methoxybenzoates of heavier trivalent lanthanides". . p. 149 - 155. Retrieved 2006.
• 6、 Li, Jian-Jun,Cao, Jun-Gang. "Investigating the formation and magnetic properties of the Dy0.75Fe1.25O3 orthoferrite prepared by sol-gel method". . p. 3997 - 4000. Retrieved 2009.
• 7、 Xing, Xianran,Dai, Shuyu,Zhu, Zhenqi,Tanaka, Toshihiro. "Thermodynamic re-optimization of the DyCl3-KCl system". . p. 31 - 35. Retrieved 2002.
• 8、 Bannach,Schnitzler,Treu Filho,Utuni,Ionashiro. "Synthesis, characterization and thermal studies on solid compounds of 2-chlorobenzylidenepyruvate of heavier trivalent lanthanides and yttrium(III)". . p. 233 - 240. Retrieved 2006.
• 9、 Sun, Yan-Hui,Zhang, Li-Qing,Lei, Peng-Xiang,Wang, Zhi-Chang,Guo, Lei. "Stepwise chlorination-chemical vapor transport reaction for rare earth oxide mixtures Gd2O3-Tb4O7, Tb4O7-Dy2O3 and Dy2O3-Ho2O3". . p. 196 - 199. Retrieved 2002.
• 10、 Chojnacka, I.,Rycerz, L.,Berkani, M.,Gaune-Escard, M.. "Phase diagram and electrical conductivity of the DyBr3-RbBr binary system". . p. 481 - 488. Retrieved 2012/06/04.