Dimethyl peroxide

Base Information

• Chemical Name: Dimethyl peroxide
• CAS No.: 690-02-8
• Molecular Formula: C2H6O2
• Molecular Weight: 62.0684
• Hs Code.: 2909600000
• DSSTox Substance ID: DTXSID40219038
• Nikkaji Number: J142.053D
• Wikidata: Q27116633
• Metabolomics Workbench ID: 44874
• Mol file: 690-02-8.mol

Synonyms:Dimethyl peroxide;Methyl peroxide;Peroxide, dimethyl;(Methylperoxy)methane;690-02-8;(Methylperoxy)methane #;CHEBI:35928;(CH3O)2;DTXSID40219038;Q27116633

Chemical Property of Dimethyl peroxide

Chemical Property:

• Vapor Pressure: 4870mmHg at 25°C
• Melting Point: -100°C
• Refractive Index: 1.3220 (estimate)
• Boiling Point: 40.6°C (rough estimate)
• PSA: 18.46000
• Density: 0.835g/cm³
• LogP: 0.19420
• XLogP3: 0.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 62.036779430
• Heavy Atom Count: 4
• Complexity: 6

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COOC

Technology Process of Dimethyl peroxide

There total 10 articles about Dimethyl peroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methane (34557-54-5,27936-85-2) → methanol (67-56-1) + formaldehyd (50-00-0,30525-89-4,61233-19-0) + methyl hydroperoxide (3031-73-0) + dimethyl peroxide (690-02-8)

Guidance literature:

With chlorine; In gas; under 30 Torr; Product distribution; Mechanism; Irradiation;

DOI:10.1021/j150607a028

Reference yield:

methylperoxy radical (2143-58-0) → methanol (67-56-1) + formaldehyd (50-00-0,30525-89-4,61233-19-0) + dimethyl peroxide (690-02-8)

Guidance literature:

at 298 ℃; under 50 - 700 Torr; Rate constant; Irradiation; in presence of He or N₂ or SF₆;

DOI:10.1021/j100450a002

Reference yield:

(Z)-azomethane (4143-42-4,503-28-6) → methanol (67-56-1) + formaldehyd (50-00-0,30525-89-4,61233-19-0) + methyl hydroperoxide (3031-73-0) + dimethyl peroxide (690-02-8)

Guidance literature:

In gas; under 0.5 - 4 Torr; Product distribution; Mechanism; Irradiation;

DOI:10.1021/j150607a028

upstream raw materials:

methane

(Z)-azomethane

dihydroxymethyl radical

methylperoxy radical

Downstream raw materials:

methyl nitrite

1,1,2,2-Tetramethyl-3-phenylcyclopropane

1-methoxy-2,2,3,3-tetramethyl-1-phenylcyclopropane

formaldehyd

Refernces

• 1、 Schuchmann, Heinz-Peter,Sonntag, Clemens von. "Methylperoxyl Radicals: A Study of the γ-Radiolysis of Methane in Oxygenated Aqueous Solutions". . p. 217 - 221. Retrieved 2007/10/02.
• 2、 Sander, Stanley,Watson, Robert T.. "Temperature Dependence of the Self-Reaction of CH3O2 Radicals". . p. 2960 - 2965. Retrieved 2007/10/02.