Gallium, dichloro(2,4,6-trimethylphenyl)-

Base Information

Chemical Name:Gallium, dichloro(2,4,6-trimethylphenyl)-
CAS No.:109391-14-2
Molecular Formula:C9H11Cl2Ga
Molecular Weight:259.815
Hs Code.:
DSSTox Substance ID:DTXSID80476587
Wikidata:Q82308124
Mol file:109391-14-2.mol

Synonyms:Gallium, dichloro(2,4,6-trimethylphenyl)-;109391-14-2;DTXSID80476587

Suppliers and Price of Gallium, dichloro(2,4,6-trimethylphenyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Gallium, dichloro(2,4,6-trimethylphenyl)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:257.94935
Heavy Atom Count:12
Complexity:138

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=C(C(=C1)C)[Ga](Cl)Cl)C

Technology Process of Gallium, dichloro(2,4,6-trimethylphenyl)-

There total 2 articles about Gallium, dichloro(2,4,6-trimethylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.5%

: 13450-90-3
Gallium trichloride

: 60607-12-7
trimesitylgallium

: 109391-14-2
mesitylgallium dichloride

Guidance literature:: In benzene; GaMes3 and GaCl3 in 1:2 molar ratio in benzene were stirred at room temp. for 18 h under inert atmosphere; benzene was removed by vac. distn., residue was washed with pentane, dried under high vac. for several hours; product can be further purifued by vac. sublimation at 140°C; elem. anal.;
DOI:10.1021/om00153a010

Reference yield: 47.0%

: 13450-90-3
Gallium trichloride

: 5806-59-7
mesityllithium

: 109391-14-2
mesitylgallium dichloride

Guidance literature:: In hexane; under N2 or Ar; dropwise addn. of a suspn. of mesityllithium in hexane to GaCl3 in hexane at -63°C under stirring, stirred for 1 h at -63°C and for 14 h at room temp.; volatiles were removed under reduced pressure, distilled at 150°Cand 4.0E-3 Torr;
DOI:10.1021/om000675a