Benzene, (1-methoxy-2-methyl-2-propenyl)-

Base Information

Chemical Name:Benzene, (1-methoxy-2-methyl-2-propenyl)-
CAS No.:142024-56-4
Molecular Formula:C11H14O
Molecular Weight:162.232
Hs Code.:
DSSTox Substance ID:DTXSID40475970
Nikkaji Number:J1.753.252I

Synonyms:Benzene, (1-methoxy-2-methyl-2-propenyl)-;142024-56-4;DTXSID40475970

Suppliers and Price of Benzene, (1-methoxy-2-methyl-2-propenyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Benzene, (1-methoxy-2-methyl-2-propenyl)-

Chemical Property:

XLogP3:3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:162.104465066
Heavy Atom Count:12
Complexity:145

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(=C)C(C1=CC=CC=C1)OC

Technology Process of Benzene, (1-methoxy-2-methyl-2-propenyl)-

There total 3 articles about Benzene, (1-methoxy-2-methyl-2-propenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 103729-80-2
2-methyl-1-phenylprop-2-en-1-ol

: 74-88-4
methyl iodide

: 142024-56-4
3-methoxy-2-methyl-3-phenyl-1-propene

Guidance literature:: 2-methyl-1-phenylprop-2-en-1-ol; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.166667h;

methyl iodide; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 6h;
DOI:10.1021/ja052245n

Reference yield:

: 100-52-7
benzaldehyde

: 142024-56-4
3-methoxy-2-methyl-3-phenyl-1-propene

Guidance literature:: Multi-step reaction with 2 steps

1.1: Mg / diethyl ether / 20 °C

1.2: 80 percent / diethyl ether / 0 - 20 °C

2.1: n-BuLi / hexane; tetrahydrofuran / 0.17 h / 0 °C

2.2: 41 percent / hexane; tetrahydrofuran / 6 h / 0 - 20 °C

With n-butyllithium; magnesium; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1021/ja052245n

Reference yield:

: 67-56-1
methanol

: 55027-62-8,81651-71-0,55027-61-7
trans-1-methyl-2-phenylcyclopropyl bromide

: 57051-05-5
2-Methoxymethyl-1-phenyl-propen-⁽¹⁾

: 142024-56-4
3-methoxy-2-methyl-3-phenyl-1-propene

Guidance literature:: With silver perchlorate; calcium carbonate; for 24h; Yield given. Yields of byproduct given; Ambient temperature;
DOI:10.1246/bcsj.65.959