bis(η-cyclopentadienyl)(μ-carbonyl)(μ-bis(diphenylphosphino)methane)(μ-copperchloride)dirhodium

Base Information

Chemical Name:bis(η-cyclopentadienyl)(μ-carbonyl)(μ-bis(diphenylphosphino)methane)(μ-copperchloride)dirhodium
CAS No.:110682-61-6
Molecular Formula:C₃₆H₃₂CuIOP₂Rh₂
Molecular Weight:938.858
Hs Code.:

Synonyms:bis(η-cyclopentadienyl)(μ-carbonyl)(μ-bis(diphenylphosphino)methane)(μ-copperchloride)dirhodium

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis(η-cyclopentadienyl)(μ-carbonyl)(μ-bis(diphenylphosphino)methane)(μ-copperchloride)dirhodium

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Technology Process of bis(η-cyclopentadienyl)(μ-carbonyl)(μ-bis(diphenylphosphino)methane)(μ-copperchloride)dirhodium

There total 1 articles about bis(η-cyclopentadienyl)(μ-carbonyl)(μ-bis(diphenylphosphino)methane)(μ-copperchloride)dirhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 7681-65-4
copper(l) iodide

: 88979-33-3
{bis(η-cyclopentadienyl)(μ-carbonyl)(μ-bis(diphenylphosphinomethane))dirhodium}

: 110682-61-6
bis(η-cyclopentadienyl)(μ-carbonyl)(μ-bis(diphenylphosphino)methane)(μ-copperchloride)dirhodium

Guidance literature:: In benzene; solid CuI was added to a soln. of Rh2-complex in benzene under nitrogen, mixt. was allowed to stir at room temp. for 150 min; isolated upon crystn. from a CH2Cl2-Et2O soln.; elem. anal.;

Reference yield: 48.5%

: 110682-61-6
bis(η-cyclopentadienyl)(μ-carbonyl)(μ-bis(diphenylphosphino)methane)(μ-copperchloride)dirhodium

: 2966-50-9
silver trifluoroacetate

: 101835-32-9
Rh₂(C₅H₅)2(CO)((C₆H₅)2PCH₂P(C₆H₅)2)(AgO₂CCF₃)

Guidance literature:: In dichloromethane; a CH2Cl2 soln. of Rh2Cu-cluster was treated with a soln. of CF3COOAg in CH2Cl2 under nitrogen, mixt. was stirred for ca. 1 h; evapd., residue was extd. with benzene, Et2O added to the ext., ppt. was recrystd. from CH2Cl2-hexane; elem. anal.;

Reference yield:

: 110682-61-6
bis(η-cyclopentadienyl)(μ-carbonyl)(μ-bis(diphenylphosphino)methane)(μ-copperchloride)dirhodium

: 88979-33-3
{bis(η-cyclopentadienyl)(μ-carbonyl)(μ-bis(diphenylphosphinomethane))dirhodium}

: 47107-74-4
tetrameric (triphenylphosphine)copper(I) iodide

Guidance literature:: With triphenyl phosphine; In dichloromethane; a stoich. amount of PPh3 was added to a CH2Cl2 soln. of Rh2Cu-cluster under N2, mixt. was stirred for ca. 30 min at room temp.; evapd., residue was extd. with Et2O, Rh2-complex was isolated from the ext., solid residue was characterized as Cu(PPh3)I by comparison with autentic sample;