Bis(benzonitrile)dichloroplatinum

Base Information

Chemical Name:Bis(benzonitrile)dichloroplatinum
CAS No.:15617-19-3
Molecular Formula:C₁₄H₁₀Cl₂N₂Pt
Molecular Weight:472.233
Hs Code.:
European Community (EC) Number:238-943-7

Synonyms:14873-63-3;Bis(benzonitrile)dichloroplatinum(II);Dichlorobis(benzonitrile)platinum(II);Bis(benzonitrile)dichloroplatinum;benzonitrile;dichloroplatinum;cis-Bis(benzonitrile)dichloroplatinum(II);15617-19-3;EINECS 238-943-7;C12H10Cl2N2Pt;C12-H10-Cl2-N2-Pt;Platinum, bis(benzonitrile)dichloro-, cis-;C14H10Cl2N2Pt;Platinum, bis(benzonitrile)dichloro-, (SP-4-2)-;Platinum, bis(benzonitrile)dichloro-;MFCD00013125;PtCl2(PhCN)2;SCHEMBL288445;C14-H10-Cl2-N2-Pt;AKOS015888404;SC10696;FT-0624707;E81057;cis-Bis(benzonitrile)dichloroplatinum(II), 98%;BIS(BENZONITRILE)DICHLOROPLATINATE (II);BIS(BENZONITRILE)DICHLOROPLATINUM(II);CIS-BIS(BENZONITRILE)DICHLOROPLATINUM(II);DICHLOROBIS(BENZONITRILE)PLATINUM(II)

Suppliers and Price of Bis(benzonitrile)dichloroplatinum

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
cis-Bis(benzonitrile)dichloroplatinum(II) 98%
500mg
$ 143.00

American Custom Chemicals Corporation
CIS-BIS-(BENZONITRILE)DICHLOROPLATINUM-(II) 95.00%
0.5G
$ 314.00

Total 30 raw suppliers

Chemical Property of Bis(benzonitrile)dichloroplatinum

Chemical Property:

Appearance/Colour:Pale yellow micro-crystals
Melting Point:224 °C (dec.)(lit.)
Boiling Point:191.1 °C at 760 mmHg
Flash Point:71.7 °C
PSA：127.31000
LogP:1.90120
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:470.986898
Heavy Atom Count:19
Complexity:106

Purity/Quality:

99%, ^*data from raw suppliers

cis-Bis(benzonitrile)dichloroplatinum(II) 98% ^*data from reagent suppliers

Safty Information:

Pictogram(s): T
Hazard Codes:T

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:C1=CC=C(C=C1)C#N.C1=CC=C(C=C1)C#N.Cl[Pt]Cl
Uses Catalyst for: Asymmetric hydroformylation reactions Allylation reactions Carbene insertion into O-H bonds of alcohols Cyclopropanation reactions Hydrosilylation reacttions Catalyst for:Asymmetric hydroformylation reactionsAllylation reactionsCarbene insertion into O-H bonds of alcoholsCyclopropanation reactionsHydrosilylation reactions

Technology Process of Bis(benzonitrile)dichloroplatinum

There total 10 articles about Bis(benzonitrile)dichloroplatinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.2%

: 100-47-0
benzonitrile

: 10025-65-7
platinum(II) chloride

: 14873-63-3,15617-19-3,51921-56-3
bis(benzonitrile)dichloroplatinum(II)

Guidance literature:: In benzonitrile; inert atmosphere; 100°C, 20 min; hot filtration (Celite), pptn. on addn. of hexanes, collection (filtration), washing (hexanes);
DOI:10.1016/s0020-1693(97)05642-9

Reference yield: 88.0%

: 100-47-0
benzonitrile

: 10025-65-7
platinum(II) chloride

: 14873-63-3,15617-19-3,51921-56-3
trans-bis(benzonitrile)dichloroplatinum(II)

Guidance literature:: In benzonitrile; suspn. of Pt compd. in benzonitrile was stirred at 100°C for 3 h; cooled to room temp.; petroleum ether added; filtered; washed (petrol ether); extd. (CH2Cl2); filtered; evapd.; chromd. (SiO2, CH2Cl2);
DOI:10.1039/b807410k

Reference yield: 80.0%

: 100-47-0
benzonitrile

: 10025-65-7
platinum(II) chloride

: 14873-63-3
cis-bis(benzonitrile)dichloroplatinum(II)

: 14873-63-3,15617-19-3,51921-56-3
trans-bis(benzonitrile)dichloroplatinum(II)

Guidance literature:: In neat (no solvent); refluxed at 100°C for 1 h; hot filtered, pumped to dryness, treated with hot benzene, filtered, residue washed (petroleum ether), dried under vacuo (yields the cis-isomer), the same procedure with the benzene-soln. gave the trans-isomer; elem. anal.;
DOI:10.1016/S0020-1693(00)84996-8