1-But-3-enylnaphthalene

Base Information

• Chemical Name: 1-But-3-enylnaphthalene
• CAS No.: 2489-88-5
• Molecular Formula: C14H14
• Molecular Weight: 182.265
• DSSTox Substance ID: DTXSID50343191
• Nikkaji Number: J861.835F
• Wikidata: Q82114430
• Mol file: 2489-88-5.mol

Synonyms:1-But-3-enylnaphthalene;1-(3-Butenyl)naphthalene;2489-88-5;1-(3-Butenyl)naphthalene #;DTXSID50343191;AKOS006325835;1-(BUT-3-EN-1-YL)NAPHTHALENE

Chemical Property of 1-But-3-enylnaphthalene

Chemical Property:

• XLogP3: 5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 182.109550447
• Heavy Atom Count: 14
• Complexity: 183

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C=CCCC1=CC=CC2=CC=CC=C21

Technology Process of 1-But-3-enylnaphthalene

There total 3 articles about 1-But-3-enylnaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

diphenyl diselenide (1666-13-3) + 4-(1-naphthyl)butane-1,2-diol bis(methanesulfonate) (151864-83-4) → 1-(but-3-en-1-yl)naphthalene (2489-88-5) + 1-(3,4-Bis-phenylselanyl-butyl)-naphthalene

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium triethylborohydride; triethylamine; In tetrahydrofuran; for 12h; Ambient temperature;

DOI:10.1021/jo962079p

Reference yield:

→ 1-butylnaphthalene (1634-09-9) + 1,2,3,4-tetrahydrophenanthrene (1013-08-7) + 1-(but-3-en-1-yl)naphthalene (2489-88-5) + 4-(1-naphthyl)-2-butene (13434-80-5)

Guidance literature:

In water; acetonitrile; for 2h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts; Irradiation;

DOI:10.1021/jo00301a030

Reference yield:

methanol (67-56-1) + 3-butenoic acid 1-naphthylmethyl ester (86328-47-4) → but-3-enoic acid (625-38-7) + 1-(but-3-en-1-yl)naphthalene (2489-88-5) + 1-(methoxymethyl)naphthalene (5903-23-1)

Guidance literature:

Irradiation;

upstream raw materials:

methanol

3-butenoic acid 1-naphthylmethyl ester

diphenyl diselenide

4-(1-naphthyl)butane-1,2-diol bis(methanesulfonate)

Downstream raw materials:

1,2-epoxy-4-(1-naphthyl)butane

dimethyl[4-(naphthalen-1-yl)butyl]phenylsilane

1-butylnaphthalene

Refernces

• 1、 Hilborn, James W.,Pincock, James A.. "Photolysis of the 1-naphthylmethyl ester of substituted phenylacetic acids: intramolecular charge transfer and rates of decarboxylation of arylacyl radicals". . p. 992 - 999. Retrieved 2007/10/02.