Benzene, 1-(2-fluoroethenyl)-4-methoxy-, (Z)-

Base Information

• Chemical Name: Benzene, 1-(2-fluoroethenyl)-4-methoxy-, (Z)-
• CAS No.: 26928-26-7
• Molecular Formula: C9H9FO
• Molecular Weight: 152.168
• Mol file: 26928-26-7.mol

Synonyms:

Chemical Property of Benzene, 1-(2-fluoroethenyl)-4-methoxy-, (Z)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzene, 1-(2-fluoroethenyl)-4-methoxy-, (Z)-

There total 17 articles about Benzene, 1-(2-fluoroethenyl)-4-methoxy-, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

(E)-[1-fluoro-2-(4-methoxyphenyl)vinyl]methyldiphenylsilane (1338228-99-1) → (Z)-1-Fluoro-2-(4-methoxyphenyl)ethylene (26928-26-7)

Guidance literature:

(E)-[1-fluoro-2-(4-methoxyphenyl)vinyl]methyldiphenylsilane; With potassium tert-butylate; In dimethyl sulfoxide; at 20 ℃; for 1h;

With water; In dimethyl sulfoxide; stereoselective reaction;

DOI:10.1021/jo201720x

Reference yield: 76.0%

3-(2,2-difluoroethenyl)anisole (1608-24-8) → (Z)-1-Fluoro-2-(4-methoxyphenyl)ethylene (26928-26-7)

Guidance literature:

With copper(I) thiophene-2-carboxylate; water; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; bis(pinacol)diborane; lithium tert-butoxide; In N,N-dimethyl acetamide; at 40 ℃; for 16h; Reagent/catalyst; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201708224

Reference yield: 75.0%

4-Methoxystyrene (637-69-4,24936-44-5) → (Z)-1-Fluoro-2-(4-methoxyphenyl)ethylene (26928-26-7)

Guidance literature:

With ruthenium trichloride; N-fluorobis(benzenesulfon)imide; In toluene; at 80 ℃; for 24h; Kinetics; Molecular sieve;

DOI:10.1039/c5cc01407g

upstream raw materials:

trichlorofluoromethane

4-methoxy-benzaldehyde

1-Heptyne

1-bromo-1-fluoro-2-(4-methoxy-phenyl)-ethylene

Downstream raw materials:

(E)-1-(3,3-dimethylbut-1-en-1-yl)-4-methoxybenzene

(E)-1-methoxy-4-(3-methyl-but-1-en-1-yl)benzene

(Z)-1-methoxy-4-(3-methylbut-1-en-1-yl)benzene

(Z)-1-methoxy-4-(pent-1-en-1-yl)benzene