Diethylmethoxyborane

Base Information Edit

Chemical Name:Diethylmethoxyborane
CAS No.:7397-46-8
Molecular Formula:C5H13BO
Molecular Weight:99.9686
Hs Code.: Oral rat LD50: 235 mg/kg
European Community (EC) Number:425-380-9,616-038-1
UNII:3AH40D7L25
DSSTox Substance ID:DTXSID501014679
Nikkaji Number:J81.386I
Wikidata:Q27256969
Mol file:7397-46-8.mol

Synonyms:Diethylmethoxyborane;7397-46-8;Methoxydiethylborane;diethyl(methoxy)borane;Methyl diethylborinate;Borinic acid, diethyl-, methyl ester;Butyl(methoxy)borane;Borinic acid, B,B-diethyl-, methyl ester;UNII-3AH40D7L25;3AH40D7L25;Methoxydiethylborane 50% in tetrahydrofuran;EC 425-380-9;Diethyl methoxy borane;MFCD00013240;diethyl methoxyborane;Methoxy diethyl borane;diethyl-methoxyborane;methoxy-diethylborane;methoxydiethyl-borane;diethyl-methoxy-borane;Methyl diethylborinate #;Diethylmethoxyborane, 97%;C5H13BO;C5-H13-B-O;DTXSID501014679;BCP24411;methyl esterb,b-diethyl-borinic acid;AKOS015915365;LS-185221;FT-0624905;EN300-102558;A837987;J-520310;Q27256969

Suppliers and Price of Diethylmethoxyborane

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
Methoxydiethylborane
1g
$ 403.00

TRC
Methoxydiethylborane
50g
$ 210.00

Strem Chemicals
100g
$ 452.00

Strem Chemicals
500g
$ 348.00

Strem Chemicals
100g
$ 104.00

Sigma-Aldrich
Diethylmethoxyborane 97%
10g
$ 73.80

Sigma-Aldrich
Diethylmethoxyborane 97%
50g
$ 238.00

Sigma-Aldrich
Diethylmethoxyborane solution 1.0 M in THF
100ml
$ 109.00

Sigma-Aldrich
Diethylmethoxyborane solution 1.0 M in THF
500ml
$ 359.00

Medical Isotopes, Inc.
Methoxydiethylborane
50 g
$ 690.00

Total 122 raw suppliers

Chemical Property of Diethylmethoxyborane Edit

Chemical Property:

Vapor Pressure:84.8mmHg at 25°C
Refractive Index:n20/D 1.387(lit.)
Boiling Point:83.2 °C at 760 mmHg
Flash Point:20°F
PSA：9.23000
Density:0.717 g/cm³
LogP:1.66410
Sensitive.:Moisture Sensitive
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:100.1059452
Heavy Atom Count:7
Complexity:35.1

Purity/Quality:

≥98.0% ^*data from raw suppliers

Methoxydiethylborane ^*data from reagent suppliers

Safty Information:

Pictogram(s): F, Xn, Xi
Hazard Codes:F,Xn,Xi,C
Statements: 11-36/37/38-22-19-48/22-43-40-37-34-17-53-20/21/22
Safety Statements: 16-26-27-36/37/39-45-61-43-6

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:B(CC)(CC)OC
Uses Methoxydiethylborane is used in analytical studies as a way to identify functional groups in protonated oxygen-containing monofunctional compounds through mass spectrometry. Reactant involved in: Studying a catalyst for ring-opening metathesis polymerization / vinyl insertion polymerizationReformatsky / quaternary Claisen condensationsEnantioselective synthesis of carba-furanose sugarsBorane-mediated control radical polymerization for synthesis of fluoropolymersHomologation reactions with sulfonium ylidesTrialkylborane promoted adhesion to low surface energy plastics

Technology Process of Diethylmethoxyborane

There total 14 articles about Diethylmethoxyborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 67-56-1
methanol

: 617-86-7
triethylsilane

: 74-85-1
ethene

: 10294-34-5
boron trichloride

: 121-43-7,63156-11-6
Trimethyl borate

: 7318-82-3
ethylboronic acid dimethyl ester

: 7397-46-8
diethyl methoxy borane

Guidance literature:: In methanol; xylene; byproducts: Et3SiCl; Ar-atmosphere; mixing BCl3, Et3SiH and C2H4, distillation of EtBCl2, addn. of MeOH; collection (distillation); NMR spectroscopy;
DOI:10.1021/om00009a018