[1,1'-Biphenyl]-3-carboxylic acid, 6-methyl-

Base Information

• Chemical Name: [1,1'-Biphenyl]-3-carboxylic acid, 6-methyl-
• CAS No.: 401573-78-2
• Molecular Formula: C₁₄H₁₂O₂
• Molecular Weight: 212.248
• Mol file: 401573-78-2.mol

Synonyms:

Chemical Property of [1,1'-Biphenyl]-3-carboxylic acid, 6-methyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [1,1'-Biphenyl]-3-carboxylic acid, 6-methyl-

There total 3 articles about [1,1'-Biphenyl]-3-carboxylic acid, 6-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

2,5-dimethylbiphenyl (7372-85-2) → 2,5-biphenyldicarboxylic acid (4445-51-6) + 5-methyl-[1,1'-biphenyl]-2-carboxylic acid (92254-03-0) + 2-methyl-5-biphenylcarboxylic acid (401573-78-2)

Guidance literature:

cobalt(II) acetate; sodium bromide; In acetic acid; at 95 ℃; for 2.66667h; Further Variations:; Catalysts; molar ratio, reaction time; Kinetics; Product distribution;

DOI:10.1023/A:1012461631396

Reference yield:

2,5-dimethylbiphenyl (7372-85-2) → 5-methyl-[1,1'-biphenyl]-2-carboxylic acid (92254-03-0) + 2-methyl-5-biphenylcarboxylic acid (401573-78-2)

Guidance literature:

With oxygen; cobalt(II) acetate; manganese(II) acetate; sodium bromide; In acetic acid; at 95 ℃; for 4h;

DOI:10.1023/A:1012461631396

Reference yield:

(3-methylbuta-1,3-dien-2-yl)benzene (18476-73-8) + acrylic acid (79-10-7) → 2-methyl-5-biphenylcarboxylic acid (401573-78-2) + 2-methyl[1,1'-biphenyl]-4-carboxylic acid (178313-67-2)

Guidance literature:

With toluene; Verestern, Erhitzen des Reaktionsprodukts mit Schwefel und anschliessendes Erwaermen mit methanol. KOH;

upstream raw materials:

(3-methylbuta-1,3-dien-2-yl)benzene

acrylic acid

2,5-dimethylbiphenyl

Downstream raw materials:

C₂₂H₂₀N₂O₂S