3-Methylcyclohex-3-ene-1-carboxylic acid

Base Information

Chemical Name:3-Methylcyclohex-3-ene-1-carboxylic acid
CAS No.:54385-25-0
Molecular Formula:C8H12O2
Molecular Weight:140.182
Hs Code.:
DSSTox Substance ID:DTXSID40504471
Nikkaji Number:J1.959.140I

Synonyms:3-Methylcyclohex-3-ene-1-carboxylic acid;54385-25-0;3-Cyclohexene-1-carboxylic acid, 3-methyl-;3-Methyl-cyclohex-3-enecarboxylic acid;SCHEMBL13209238;DTXSID40504471;QYBCIXZXNMUURP-UHFFFAOYSA-N;AKOS006379754

Suppliers and Price of 3-Methylcyclohex-3-ene-1-carboxylic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 3-Methylcyclohex-3-ene-1-carboxylic acid

Chemical Property:

XLogP3:1.2
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:140.083729621
Heavy Atom Count:10
Complexity:170

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CCCC(C1)C(=O)O

Technology Process of 3-Methylcyclohex-3-ene-1-carboxylic acid

There total 14 articles about 3-Methylcyclohex-3-ene-1-carboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 79-10-7
acrylic acid

: 78-79-5,9003-31-0
isoprene

: 54385-25-0
(+/-)-3-methylcyclohex-3-ene-1-carboxylic acid

Guidance literature:: With borane-THF; In dichloromethane; at 0 ℃; for 30h;
DOI:10.1021/ja00226a055

Reference yield: 59.0%

: 79-10-7
acrylic acid

: 78-79-5,9003-31-0
isoprene

: 4342-60-3
4-methylcyclohex-3-enecarboxylic acid

: 54385-25-0
(+/-)-3-methylcyclohex-3-ene-1-carboxylic acid

Guidance literature:: at 95 ℃; for 2h; Yields of byproduct given;
DOI:10.1016/S0040-4039(00)82147-4

Reference yield:

: 814-68-6,25189-84-8
acryloyl chloride

: 78-79-5,9003-31-0
isoprene

: 54385-25-0
(+/-)-3-methylcyclohex-3-ene-1-carboxylic acid

Guidance literature:: acryloyl chloride; With 1-butyl-5-hydroxymethyl-3-methyl-3H-imidazol-1-ium NTf₂; triethylamine; 3-butyl-5-hydroxymethyl-1-methyl-3H-imidazol-1-ium triflimide; In dichloromethane; at -20 ℃; for 0.5h;

isoprene; With hydroquinone; at 120 ℃; for 12h;

With sodium hydroxide; In water; for 2h; Heating;
DOI:10.1016/j.tetlet.2003.09.121