Glycidyl acrylate

Base Information

• Chemical Name: Glycidyl acrylate
• CAS No.: 106-90-1
• Deprecated CAS: 130232-45-0,69960-65-2,70404-76-1,69960-65-2,70404-76-1
• Molecular Formula: C₆H₈O₃
• Molecular Weight: 128.128
• Hs Code.: 29280090
• European Community (EC) Number: 203-440-3
• NSC Number: 67196,24151
• UN Number: 1992
• UNII: L8N627D5ZC
• DSSTox Substance ID: DTXSID5025360
• Nikkaji Number: J33.797H
• Wikidata: Q26841212
• Mol file: 106-90-1.mol

Synonyms:2,3-EPA;2,3-epoxypropyl acrylate;glycidyl acrylate

Chemical Property of Glycidyl acrylate

Chemical Property:

• Appearance/Colour: amber liquid
• Vapor Pressure: 0.192mmHg at 25°C
• Melting Point: -42 °C
• Refractive Index: 1.4508 (589.3 nm 20℃)
• Boiling Point: 210.509 °C at 760 mmHg
• Flash Point: 76.111 °C
• PSA: 38.83000
• Density: 1.129 g/cm³
• LogP: 0.11440
• Storage Temp.: -20°C Freezer
• XLogP3: 0.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 128.047344113
• Heavy Atom Count: 9
• Complexity: 130
• Transport DOT Label: Flammable Liquid Poison

Purity/Quality:

98%,99%, ^*data from raw suppliers

Glycidyl ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 23/24/25-34-43
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Plastics & Rubber -> (Meth)acrylates
• Canonical SMILES: C=CC(=O)OCC1CO1
• Uses: Labelled Glycidyl Glycidyl Acrylate 85% can be used as an adhesive composition.

Technology Process of Glycidyl acrylate

There total 10 articles about Glycidyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

oxiranyl-methanol (556-52-5) + acryloyl chloride (814-68-6,25189-84-8) → glycidyl acrylate (106-90-1,130232-99-4,130233-00-0)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃; for 4h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/acs.macromol.6b02137

Reference yield: 27.0%

sodium 2-propenoate (7446-81-3) + epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → glycidyl acrylate (106-90-1,130232-99-4,130233-00-0)

Guidance literature:

With tetramethlyammonium chloride; hydroquinone; at 90 ℃; for 3h;

Reference yield: 27.0%

allyl acrylate (999-55-3) → glycidyl acrylate (106-90-1,130232-99-4,130233-00-0)

Guidance literature:

With sodium hydroxide; sodium tungstate; dihydrogen peroxide; Aliquat 336; In dichloromethane; phosphoric acid; at 25 ℃; for 188h;

DOI:10.1016/S0040-4020(01)90120-6

upstream raw materials:

sodium 2-propenoate

epichlorohydrin

allyl acrylate

sodium t-butanolate

Downstream raw materials:

oxiran-2-ylmethyl propionate

2-Hydroxy-3-(2-Cyano-3,3-Diphenyl acryloxy) Ethoxy Propyl Acrylate

2-hydroxyethyl acrylate

2,3-epoxypropyl 3-(phenylthio)propionate

Refernces

• 1、 Chernyshev,Belyakova,Knyazeva,Khromykh. "Hydrosilylation of allyl glycidyl ether with triethoxysilane". . p. 55 - 61. Retrieved 2007.
• 2、 -. "(Meth) acrylate having glucoskeleton methylfluorene". Paragraph 0064; 0065. . Retrieved 2016/12/12.