Sodium acrylate

Base Information

• Chemical Name: Sodium acrylate
• CAS No.: 7446-81-3
• Deprecated CAS: 124740-94-9,126123-84-0,138961-78-1,199453-47-9,44196-70-5,65852-59-7,291530-46-6,1239896-27-5,1674405-53-8,1865799-57-0,2249945-71-7,105287-10-3,170427-67-5,65852-60-0,147881-53-6,190605-99-3,1239896-27-5,126123-84-0,138961-78-1,1674405-53-8,1865799-57-0,199453-47-9,291530-46-6,44196-70-5,65852-59-7
• Molecular Formula: C3H4 O2 . Na
• Molecular Weight: 94.0454
• Hs Code.: 29161100
• European Community (EC) Number: 231-209-7,618-349-8,639-849-2,692-137-3
• ICSC Number: 1429
• UNII: 7C98FKB43H
• DSSTox Substance ID: DTXSID4027652
• Nikkaji Number: J107.533K
• Wikidata: Q15632837
• RXCUI: 1364499
• ChEMBL ID: CHEMBL3185326
• Mol file: 7446-81-3.mol

Synonyms:2-propenoic acid;acrylate;acrylic acid;acrylic acid, aluminum salt;acrylic acid, ammonium salt;acrylic acid, Ca (2:1) salt;acrylic acid, Ca (2:1) salt, dihydrate;acrylic acid, cobalt (2+) salt;acrylic acid, Fe (3+) salt;acrylic acid, magnesium salt;acrylic acid, potassium salt;acrylic acid, silver salt;acrylic acid, sodium salt;acrylic acid, zinc salt;Hystoacril;magnesium acrylate;vinylformic acid

Chemical Property of Sodium acrylate

Chemical Property:

• Appearance/Colour: solid
• Vapor Pressure: 3.42mmHg at 25°C
• Melting Point: >300 °C(lit.)
• Boiling Point: 141oC at 760 mmHg
• Flash Point: 61.6oC
• PSA: 40.13000
• Density: 1.528[at 20℃]
• LogP: -1.07770
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Water Solubility.: 479g/L at 20℃
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 94.00307362
• Heavy Atom Count: 6
• Complexity: 59.8

Purity/Quality:

99% ^*data from raw suppliers

Sodium acrylate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Plastics & Rubber -> (Meth)acrylates
• Canonical SMILES: C=CC(=O)[O-].[Na+]
• Inhalation Risk: A harmful concentration of airborne particles can be reached quickly when dispersed.
• Effects of Short Term Exposure: May cause mechanical irritation.
• Effects of Long Term Exposure: Repeated or prolonged inhalation may cause effects on the lungs.
• Uses: Sodium Acrylate is the acid form of Acrylic Acid (A191350); which is an antibacterial agent. SA can be used in tuning the grain size of iron oxide microparticles for potential applications in biological assaying and in chemical sensors. It can be used as a reducing and capping agent on gold nanoparticles which can be used in the biological application.

Technology Process of Sodium acrylate

There total 19 articles about Sodium acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.8%

acrylic acid (79-10-7) → sodium 2-propenoate (7446-81-3)

Guidance literature:

With sodium hydroxide; In water; acetone;

Reference yield: 95.0%

ethene (74-85-1) + (dtbpe)Ni(η2-sodium acrylate)complex → [bis(di-tert-butylphosphino)ethane](ethylene)nickel (138419-50-8) + sodium 2-propenoate (7446-81-3)

Guidance literature:

In tetrahydrofuran; for 18h; under 22502.3 Torr; Inert atmosphere;

DOI:10.1002/chem.201201757

Reference yield: 61.8%

3-hydroxypropanoic acid sodium salt (6487-38-3) → sodium 2-propenoate (7446-81-3)

Guidance literature:

With 1,3-dimethoxy-2-hydroxy-benzene; zirconium hydroxide; at 200 ℃; for 1 - 4h; Product distribution / selectivity;

upstream raw materials:

4-acrylamido-4-methyltetrahydrothiophene-3-sulfonic acid 1,1-dioxide

3-cyclohexanesulfonyl-propionic acid

acrylic acid

3-hydroxypropanoic acid sodium salt

Downstream raw materials:

glycidyl acrylate

acrylic acid anhydride

acryloyl chloride

succinic acid

Refernces

• 1、 Hopkins, Melissa N.,Shimmei, Kenichi,Uttley, Katherine B.,Bernskoetter, Wesley H.. "Synthesis and Reactivity of 1,2-Bis(di- iso-propylphosphino)benzene Nickel Complexes: A Study of Catalytic CO2-Ethylene Coupling". . p. 3573 - 3580. Retrieved 2018.
• 2、 Eritsyan,Barsegyan, Zh. B.,Manukyan, Sh. M.,Karapetyan. "Copolymerization of sodium acrylate with new acrylamide derivatives in the presence of water-soluble salts". . p. 1253 - 1256. Retrieved 2011.
• 3、 Manzini, Simone,Huguet, Núria,Trapp, Oliver,Schaub, Thomas. "Palladium- and Nickel-Catalyzed Synthesis of Sodium Acrylate from Ethylene, CO2, and Phenolate Bases: Optimization of the Catalytic System for a Potential Process". . p. 7122 - 7130. Retrieved 2015.
• 4、 -. "Powder composition for pack and manufacturing method thereof, microgel for sherbet-shaped beauty pack utilizing the powder composition, and manufacturing method thereof". Paragraph 0028; 0075-0076. . Retrieved 2021/01/28.