Benzeneacetic acid, 2-methoxy-a-methyl-, methyl ester

Base Information

Chemical Name:Benzeneacetic acid, 2-methoxy-a-methyl-, methyl ester
CAS No.:60779-19-3
Molecular Formula:C11H14O3
Molecular Weight:194.23
Hs Code.:

Synonyms:methyl 2-(2-methoxyphenyl)propanoate;Methyl-2-(o-methoxyphenyl)-propanoat;

Suppliers and Price of Benzeneacetic acid, 2-methoxy-a-methyl-, methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of Benzeneacetic acid, 2-methoxy-a-methyl-, methyl ester

Chemical Property:

PSA：35.53000
LogP:1.97170

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Benzeneacetic acid, 2-methoxy-a-methyl-, methyl ester

There total 8 articles about Benzeneacetic acid, 2-methoxy-a-methyl-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 27798-60-3
methyl 2-(2-methoxyphenyl)acetate

: 74-88-4
methyl iodide

: 60779-19-3
Methyl (+/-)-2-(2-Methoxyphenyl)propanoate

Guidance literature:: methyl 2-(2-methoxyphenyl)acetate; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 0.5h; Inert atmosphere;

methyl iodide; In tetrahydrofuran; at -78 - 20 ℃;

Reference yield: 91.0%

: 554-12-1
propanoic acid methyl ester

: 578-57-4
2-bromoanisole

: 60779-19-3
Methyl (+/-)-2-(2-Methoxyphenyl)propanoate

Guidance literature:: propanoic acid methyl ester; With sodium hexamethyldisilazane; In toluene; at -60 ℃; for 1.5h; Inert atmosphere; Sealed tube;

With zinc(II) chloride; In tetrahydrofuran; toluene; at -35 ℃; for 1h; Inert atmosphere; Sealed tube;

2-bromoanisole; With monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In tetrahydrofuran; toluene; at -15 - 20 ℃; for 4h; Inert atmosphere; Sealed tube;
DOI:10.1021/jo401476f

Reference yield: 18.0%

: 529-28-2
4-iodoanisol

: Methyl 2-<(methoxallyl)oxy>acetate

: 60779-19-3
Methyl (+/-)-2-(2-Methoxyphenyl)propanoate

Guidance literature:: With pyridine; nickel(II) iodide; 4,5-dihydro-2-(pyridin-2-yl)-1H-imidazole; magnesium chloride; zinc; In N,N-dimethyl acetamide; at 20 ℃; for 12h; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.orglett.9b00174