1,1,4,5-Tetramethyl-2,2-bis(trimethylsilyl)-1,2,3,6-tetrahydrosiline

Base Information

• Chemical Name: 1,1,4,5-Tetramethyl-2,2-bis(trimethylsilyl)-1,2,3,6-tetrahydrosiline
• CAS No.: 62139-57-5
• Molecular Formula: C15H34Si3
• Molecular Weight: 298.691
• DSSTox Substance ID: DTXSID10508385
• Wikidata: Q82365253
• Mol file: 62139-57-5.mol

Synonyms:62139-57-5;DTXSID10508385;1,1,4,5-Tetramethyl-2,2-bis(trimethylsilyl)-1,2,3,6-tetrahydrosiline

Chemical Property of 1,1,4,5-Tetramethyl-2,2-bis(trimethylsilyl)-1,2,3,6-tetrahydrosiline

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 298.19683069
• Heavy Atom Count: 18
• Complexity: 350

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=C(C[Si](C(C1)([Si](C)(C)C)[Si](C)(C)C)(C)C)C

Technology Process of 1,1,4,5-Tetramethyl-2,2-bis(trimethylsilyl)-1,2,3,6-tetrahydrosiline

There total 4 articles about 1,1,4,5-Tetramethyl-2,2-bis(trimethylsilyl)-1,2,3,6-tetrahydrosiline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,2-Dimethyl-4,4-diphenyl-3,3-bis(trimethylsilyl)-1-oxa-2-silacyclobutan (80431-43-2) + 2,3-dimethyl-buta-1,3-diene (513-81-5) → benzophenone (119-61-9) + bis(trimethylsilyl)methan (80980-06-9) + 1,1,3,4-Tetramethyl-6,6-bis(trimethylsilyl)-1-sila-3-cyclohexen (62139-57-5)

Guidance literature:

With chloro-trimethyl-silane; In diethyl ether; at 120 ℃; for 20h; Product distribution; various reactants;

Reference yield:

2,2-Dimethyl-4,4-diphenyl-1,3,3-tris(trimethylsilyl)-1-aza-2-silacyclobutan (80431-36-3) + 2,3-dimethyl-buta-1,3-diene (513-81-5) → diphenylmethyleneaminotrimethylsilane (17599-59-6) + bis(trimethylsilyl)methan (80980-06-9) + 1,1,3,4-Tetramethyl-6,6-bis(trimethylsilyl)-1-sila-3-cyclohexen (62139-57-5)

Guidance literature:

In diethyl ether; at 80 ℃; for 72h;

Reference yield:

2,3,4,4a-Tetrahydro-3,3-dimethyl-1-phenyl-2,4,4-tris(trimethylsilyl)-2-aza-3-silanaphthalin (80431-44-3) + 2,3-dimethyl-buta-1,3-diene (513-81-5) → diphenylmethyleneaminotrimethylsilane (17599-59-6) + bis(trimethylsilyl)methan (80980-06-9) + 1,1,3,4-Tetramethyl-6,6-bis(trimethylsilyl)-1-sila-3-cyclohexen (62139-57-5)

Guidance literature:

In diethyl ether; at 80 ℃; for 72h;

upstream raw materials:

benzophenone

2,2-Dimethyl-4,4-diphenyl-1,3,3-tris(trimethylsilyl)-1-aza-2-silacyclobutan

2,3-dimethyl-buta-1,3-diene

2,2-Dimethyl-4,4-diphenyl-3,3-bis(trimethylsilyl)-1-oxa-2-silacyclobutan