N-(p-Chlorobenzylidene)methylamine

Base Information

• Chemical Name: N-(p-Chlorobenzylidene)methylamine
• CAS No.: 13114-22-2
• Molecular Formula: C8H8 Cl N
• Molecular Weight: 153.611
• Hs Code.: 2925290090
• European Community (EC) Number: 854-504-8
• Nikkaji Number: J29.994D
• Mol file: 13114-22-2.mol

Synonyms:13114-22-2;N-(p-Chlorobenzylidene)methylamine;1-(4-chlorophenyl)-N-methylmethanimine;N-[(4-CHLOROPHENYL)METHYLENE]METHANAMINE;[(4-chlorophenyl)methylidene](methyl)amine;Methananime, N-((4-chlorophenyl)methylene)-;SCHEMBL1613354;SCHEMBL11260669;ETHYL5H-OCTAFLUOROPENTANOATE;N-(4-CHLOROBENZYLIDENE)METHYLAMINE;Methanamine, N-[(4-chlorophenyl)methylene]-;EN300-345548;N-[(E)-(4-chlorophenyl)methylidene]methanamine

Chemical Property of N-(p-Chlorobenzylidene)methylamine

Chemical Property:

• Vapor Pressure: 0.00879mmHg at 25°C
• Boiling Point: 266.2°C at 760 mmHg
• Flash Point: 114.8°C
• PSA: 12.36000
• Density: 1.185g/cm³
• LogP: 2.38870
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 153.0345270
• Heavy Atom Count: 10
• Complexity: 114

Purity/Quality:

99% ^*data from raw suppliers

N-(4-chlorobenzylidene)methanamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN=CC1=CC=C(C=C1)Cl

Technology Process of N-(p-Chlorobenzylidene)methylamine

There total 9 articles about N-(p-Chlorobenzylidene)methylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-chlorobenzaldehyde (104-88-1) + methylamine (74-89-5) → N-(4-chlorobenzylidene)methylamine (13114-22-2)

Guidance literature:

at 20 ℃; for 12h;

DOI:10.1055/s-0029-1218796

Reference yield: 99.0%

4-chlorobenzaldehyde (104-88-1) + methylammonium N-methylcarbamate (65398-48-3) → N-(4-chlorobenzylidene)methylamine (13114-22-2)

Guidance literature:

In neat (no solvent); at 25 ℃; for 3h; Inert atmosphere; Green chemistry;

DOI:10.1039/d0ra07814j

Reference yield: 96.0%

methylamine hydrochloride (593-51-1) + 4-chlorobenzaldehyde (104-88-1) → N-(4-chlorobenzylidene)methylamine (13114-22-2)

Guidance literature:

With 1,1'-(1,4-butanediyl)bis(imidazole); In neat (no solvent); at 20 ℃; for 10h; Milling;

DOI:10.1071/CH18408

upstream raw materials:

methylamine hydrochloride

4-chlorobenzaldehyde

methylamine

C₁₅H₁₃ClF₃NO₃S

Downstream raw materials:

N-[4-chloro-α-(4-chloro-benzylidenamino)-benzyl]-formamide

4,6-bis-(4-chloro-phenyl)-3,5-dimethyl-[1,3,5]thiadiazinane-2-thione

4-(4-chloro-phenyl)-5-methyl-2,6-bis-(2,2,2-trifluoro-1-trifluoromethyl-ethylidene)-[1,3,5]dithiazinane

3-(4-chloro-phenyl)-2-methyl-2,3-dihydro-9H-indeno[2,1-e][1,4,3]oxathiazine 1,1-dioxide