Ethyl 4-oxocyclohex-1-ene-1-carboxylate

Base Information

Chemical Name:Ethyl 4-oxocyclohex-1-ene-1-carboxylate
CAS No.:67311-98-2
Molecular Formula:C9H12O3
Molecular Weight:168.192
Hs Code.:
DSSTox Substance ID:DTXSID60553007
Wikidata:Q82433472

Synonyms:67311-98-2;Ethyl 4-oxocyclohex-1-ene-1-carboxylate;DTXSID60553007

Suppliers and Price of Ethyl 4-oxocyclohex-1-ene-1-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Ethyl 4-oxocyclohex-1-ene-1-carboxylate

Chemical Property:

XLogP3:0.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:168.078644241
Heavy Atom Count:12
Complexity:228

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1=CCC(=O)CC1

Technology Process of Ethyl 4-oxocyclohex-1-ene-1-carboxylate

There total 5 articles about Ethyl 4-oxocyclohex-1-ene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 865-49-6
chloroform-d1

: 72653-21-5
ethyl 1-acetyl-4-oxocyclohexane-1-carboxylate

: 33685-54-0
1,1,2,2-tetrachloroethane-d₂

: 1665-01-6
dichloromethane-d1

: 67311-98-2
ethyl 4-oxocyclohex-1-enecarboxylate

: 75-07-0,9002-91-9
acetaldehyde

: 75-36-5
acetyl chloride

: C₁₀H₁₃⁽²⁾HCl₂O₃

Guidance literature:: at 19.9 ℃; for 0.333333h; Mechanism; Irradiation;
DOI:10.1002/mrc.1260270506

Reference yield:

: 38053-91-7
2-trimethylsilyloxy-1,3-butadiene

: 623-47-2
propynoic acid ethyl ester

: 104331-18-2
ethyl 4-oxocyclohex-2-enecarboxylate

: 67311-98-2
ethyl 4-oxocyclohex-1-enecarboxylate

Guidance literature:: Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1016/S0040-4039(00)95031-7

Reference yield:

: 623-47-2
propynoic acid ethyl ester

: 67311-98-2
ethyl 4-oxocyclohex-1-enecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 77.3 percent / hydroquinone / benzene / 24 h / 140 °C

2: sulphuric acid / tetrahydrofuran; H₂O / 1 h / Ambient temperature

With sulfuric acid; hydroquinone; In tetrahydrofuran; water; benzene;
DOI:10.1039/P19870002689