CID 66390

Base Information

Chemical Name:CID 66390
CAS No.:13537-33-2
Molecular Formula:FH₃Si
Molecular Weight:50.1077
Hs Code.:
Nikkaji Number:J1.573.742E,J215.223A
Wikidata:Q16712763
Mol file:13537-33-2.mol

Synonyms:

Suppliers and Price of CID 66390

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of CID 66390

Chemical Property:

Boiling Point:-98°C (estimate)
PSA：0.00000
LogP:0.00000
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:49.99880479
Heavy Atom Count:2
Complexity:2

Purity/Quality:: 98%Min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:F[SiH3]

Technology Process of CID 66390

There total 46 articles about CID 66390 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 7647-19-0,874483-74-6
phosphorus pentafluoride

: 36875-96-4
difluoro(silylamino)phosphine

: 11128-24-8,13537-33-2
fluorosilane

: 71481-55-5
difluorophosphino(tetrafluorophosphoranyl)amine

Guidance literature:: In neat (no solvent); absence of air and moisture (vac. line); slight excess of PF5, warming to room temp. for 15 s; fractional condensation (vac.);
DOI:10.1039/DT9790001070

Reference yield: 90.0%

: 7783-81-5
uranium hexafluoride

: 7440-21-3
monosilane

: 11128-24-8,13537-33-2
fluorosilane

UF(4-4.5): UF(4-4.5)

Guidance literature:: In gas; byproducts: fluorosilanes; UF6 (40 Torr), SiH4 (48 or 34 Torr); 25 min at 145°C; (reaction onset at 135°C);
DOI:10.1063/1.437914

Reference yield: 87.0%

: 14791-57-2
silyl bromide

: 34326-59-5
bis(difluorophosphino)amine

: 75-50-3
trimethylamine

: 11128-24-8,13537-33-2
fluorosilane

: 71579-72-1
bis(difluorophosphino)silylamine

: 7783-55-3
trifluorophosphane

Guidance literature:: In neat (no solvent); byproducts: (NHMe3)Br; absence of air and moisture (vac. line); condensing NMe3 onto mixt. of NH(PF2)2 and SiBrH3, warming to room temp. for 15 s; fractional distn.;
DOI:10.1039/DT9790001065