Stannane, [1,2-phenylenebis(methylene)]bis[trimethyl-

Base Information

Chemical Name:Stannane, [1,2-phenylenebis(methylene)]bis[trimethyl-
CAS No.:84457-41-0
Molecular Formula:C14H26Sn2
Molecular Weight:431.78
Hs Code.:

Synonyms:

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Chemical Property of Stannane, [1,2-phenylenebis(methylene)]bis[trimethyl-

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of Stannane, [1,2-phenylenebis(methylene)]bis[trimethyl-

There total 2 articles about Stannane, [1,2-phenylenebis(methylene)]bis[trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 612-12-4
o-Xylylene dichloride

: 1066-45-1
trimethyltin(IV)chloride

: 19962-44-8
α-(trimethylstannyl)-o-xylene

: 84457-41-0
α,alpha'.-bis(trimethylstannyl)-o-xylene

Guidance literature:: With magnesium; ethylene dibromide; In tetrahydrofuran; inert atmosphere, activation of Mg with ethylene bromide in THF, addn. of THF and a further portion of ethylene bromide, reflux, addn. of soln. of dichloro-o-xylene and soln. of (CH3)3SnCl to the boiling soln., reflux (6 h); saturated aq. NH4Cl, extn. (Et2O), washing of extracts (water), drying (Na2SO4), concn. (reduced pressure), distillation (92-95°C, 0.05 Torr);
DOI:10.1002/(SICI)1099-0682(199806)1998:6<761::AID-EJIC761>3.0.CO;2-1

Reference yield: 72.0%

: 1066-45-1
trimethyltin(IV)chloride

: 78499-87-3
bis(chloromagnesiummethyl)benzol

: 84457-41-0
α,alpha'.-bis(trimethylstannyl)-o-xylene

Guidance literature:: In tetrahydrofuran; a soln. of Me3SnCl was added to a soln. of organomagnesium, refluxed for 1 h; hydrolysis, distillation;
DOI:10.1016/S0022-328X(00)84800-7

Reference yield: 85.0%

: 10294-34-5
boron trichloride

: 84457-41-0
α,alpha'.-bis(trimethylstannyl)-o-xylene

: 208246-71-3
α,.alpha'.-bis(trichlorodimethylstannyl)-o-xylene

Guidance literature:: In hexane; pentane; byproducts: CH3BCl2; inert atmosphere, addn. of hexane soln. of BCl3 to pentane soln. of stannyl compound at -50°C (15 h), stirring (-50°C, 2 h), warming to room temp., stirring (room temp., 12 h); filtration, washing (pentane), drying (room temp., 1 Torr);
DOI:10.1002/(SICI)1099-0682(199806)1998:6<761::AID-EJIC761>3.0.CO;2-1