Thulium Chloride Solution

Base Information

• Chemical Name: Thulium Chloride Solution
• CAS No.: 13537-18-3
• Molecular Formula: Cl3Tm
• Molecular Weight: 275.293
• UNII: 73TYF012WF
• Nikkaji Number: J134.252E
• Mol file: 13537-18-3.mol

Synonyms:Cl3Tm;Cl3-Tm;Thulium chloride(TmCl3);Thulium Chloride Solution;AKOS025294381;Thulium chloride heptahydrate (as TmCl3)

Chemical Property of Thulium Chloride Solution

Chemical Property:

• Appearance/Colour: yellow
• Vapor Pressure: 33900mmHg at 25°C
• Melting Point: 821 ºC
• Boiling Point: 1490ºC
• Flash Point: °C
• PSA: 0.00000
• Density: 3.98 g/cm³
• LogP: -8.98800
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 273.840777
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Tm+3]

Technology Process of Thulium Chloride Solution

There total 16 articles about Thulium Chloride Solution which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[Tm(chloride)2(water)6]Cl → thulium(III) chloride (13537-18-3)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O; Schlenk techniques; heating Tm compd. under vacuum (1E-3 Torr);

DOI:10.1016/j.poly.2010.02.027

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + thulia → thulium(III) chloride (13537-18-3)

Guidance literature:

In hydrogenchloride; metal oxide treated with concd. HCl; soln. evapd. to near dryness;

DOI:10.1016/j.tca.2006.09.014

Reference yield:

thulia + chlorine (7782-50-5) → thulium(III) chloride (13537-18-3)

Guidance literature:

With pyrographite; In solid; byproducts: CO; at 800°C for 2 h;

DOI:10.1016/j.jallcom.2006.09.121

upstream raw materials:

aluminium trichloride

hydrogenchloride

chlorine

thulium(III) chloride hydrate

Downstream raw materials:

thulium

Tm(H₂NSO₂C₆H₄NCHC₆H₄O)3(H₂O)2

Refernces

• 1、 Grimm, Judith,Suyver, J. Freek,Beurer, Eva,Carver, Graham,Guedel, Hans U.. "Light-emission and excited-state dynamics in Tm2+ doped CsCaCl3, CsCaBr3, and CsCaI3". . p. 2093 - 2101. Retrieved 2006.
• 2、 Chen, Huan,Zhai, Xuesong,Li, Duo,Wang, Lili,Zhao, Dan,Qin, Weiping. "Water-soluble Yb3+, Tm3+ codoped NaYF4 nanoparticles: Synthesis, characteristics and bioimaging". . p. 70 - 73. Retrieved 2011/12/13.
• 3、 Ambrozini, B.,Dametto, P. R.,Ionashiro, M.. "Synthesis, characterization and thermal behaviour of solid-state tartrates of heavy trivalent lanthanides and yttrium(III)". . p. 867 - 871. Retrieved 2011/10/31.