Methyl 4'-chloro[1,1'-biphenyl]-4-carboxylate

Base Information

Chemical Name:Methyl 4'-chloro[1,1'-biphenyl]-4-carboxylate
CAS No.:89901-02-0
Molecular Formula:C14H11 Cl O2
Molecular Weight:246.693
Hs Code.:2916399090
European Community (EC) Number:687-287-1
DSSTox Substance ID:DTXSID90353274
Nikkaji Number:J622.834H
Wikidata:Q82130753
Mol file:89901-02-0.mol

Synonyms:89901-02-0;methyl 4-(4-chlorophenyl)benzoate;Methyl 4'-chloro[1,1'-biphenyl]-4-carboxylate;Methyl 4'-chloro-[1,1'-biphenyl]-4-carboxylate;methyl 4'-chlorobiphenyl-4-carboxylate;MFCD04117794;SCHEMBL14926631;DTXSID90353274;AKOS002679497;Methyl 4-(4-chlorophenyl)benzoate, 95%;BB 0222608;CS-0189017;FT-0680240;E89778;4'-Chlorobiphenyl-4-carboxylic acid methyl ester;2X-0700;J-522326

Suppliers and Price of Methyl 4'-chloro[1,1'-biphenyl]-4-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl 4-(4-chlorophenyl)benzoate
500mg
$ 85.00

SynQuest Laboratories
Methyl 4'-chloro-[1,1'-biphenyl]-4-carboxylate
5 g
$ 312.00

Sigma-Aldrich
Methyl 4-(4-chlorophenyl)benzoate 95%
1g
$ 31.40

Matrix Scientific
Methyl 4'-chloro[1,1'-biphenyl]-4-carboxylate >95%
1g
$ 454.00

Matrix Scientific
Methyl 4'-chloro[1,1'-biphenyl]-4-carboxylate >95%
500mg
$ 362.00

Matrix Scientific
Methyl 4'-chloro[1,1'-biphenyl]-4-carboxylate >95%
5g
$ 1040.00

Crysdot
Methyl4'-chloro-[1,1'-biphenyl]-4-carboxylate 95+%
5g
$ 317.00

AOBChem
Methyl4'-chloro-[1,1'-biphenyl]-4-carboxylate 97%
1g
$ 98.00

AOBChem
Methyl4'-chloro-[1,1'-biphenyl]-4-carboxylate 97%
500mg
$ 70.00

American Custom Chemicals Corporation
METHYL 4'-CHLORO[1,1'-BIPHENYL]-4-CARBOXYLATE 95.00%
5G
$ 1034.53

Total 14 raw suppliers

Chemical Property of Methyl 4'-chloro[1,1'-biphenyl]-4-carboxylate

Chemical Property:

Melting Point:113-115°C
Boiling Point:364.1oC at 760 mmHg
Flash Point:187.5oC
PSA：26.30000
Density:1.205g/cm3
LogP:3.79360
XLogP3:4.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:246.0447573
Heavy Atom Count:17
Complexity:251

Purity/Quality:

99%, ^*data from raw suppliers

Methyl 4-(4-chlorophenyl)benzoate ^*data from reagent suppliers

Safty Information:

Pictogram(s): N
Hazard Codes:N
Statements: 50/53
Safety Statements: 60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:COC(=O)C1=CC=C(C=C1)C2=CC=C(C=C2)Cl
Uses Methyl 4-(4-Chlorophenyl)benzoate is used in the preparation of ionic compound-supported palladium complex as catalyst for suzuki-Miyaura coupling of aryl halides.

Technology Process of Methyl 4'-chloro[1,1'-biphenyl]-4-carboxylate

There total 3 articles about Methyl 4'-chloro[1,1'-biphenyl]-4-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 1679-18-1
4-Chlorophenylboronic acid

: 99768-12-4
4-methoxycarbonylphenylboronic acid

: 2050-68-2
4,4'-dichlorobiphenyl

: 89901-02-0
methyl 4′-chloro-[1,1′-biphenyl]-4-carboxylate

Guidance literature:: With potassium carbonate; In water; acetonitrile; at 70 ℃; chemoselective reaction; Schlenk technique;
DOI:10.1002/asia.201800358

Reference yield: 33.0%

: 5-(4-chlorophenyl)-5H-thianthren-5-ium trifluoromethanesulfonate

: 99768-12-4
4-methoxycarbonylphenylboronic acid

: 89901-02-0
methyl 4′-chloro-[1,1′-biphenyl]-4-carboxylate

Guidance literature:: With bis(tri-t-butylphosphine)palladium⁽⁰⁾; sodium hydrogencarbonate; In dichloromethane; N,N-dimethyl-formamide; at 50 ℃; for 12h; Inert atmosphere; Schlenk technique;
DOI:10.1039/d0cc00641f

Reference yield:

: 108-90-7
chlorobenzene

: 1571-08-0
methyl 4-formylbenzoate

: 89901-02-0
methyl 4′-chloro-[1,1′-biphenyl]-4-carboxylate

: 89900-96-9
2'-chlorobiphenyl-4-carboxylic acid methyl ester

: 89901-01-9
methyl 3'-chloro-[1,1'-biphenyl]-4-carboxylate

Guidance literature:: With di-tert-butyl peroxide; 1,2-Dinitrobenzene; at 150 ℃; for 12h; Overall yield = 59 %; Overall yield = 29 mg; Inert atmosphere; Sealed tube;
DOI:10.1039/c4cc10155c