Aluminium fluoride

Base Information

• Chemical Name: Aluminium fluoride
• CAS No.: 7784-18-1
• Deprecated CAS: 1328946-66-2,856859-79-5
• Molecular Formula: AlF3
• Molecular Weight: 83.9767
• Hs Code.: 2826121000
• UNII: Z77H3IKW94
• DSSTox Substance ID: DTXSID8030712
• Nikkaji Number: J43.601A
• Mol file: 7784-18-1.mol

Synonyms:Aluminium fluoride;aluminum;trifluoride;17949-86-9;fluorure d'aluminium;ALF (CHRIS Code);Al-F3;Aluminium Fluoride Powder;aluminium fluoride (aif3);Aluminium fluoride (AlF3);Aluminium fluoride (AlF3);Fluoruro de aluminio (alf3);ALUMINUM(III) FLUORIDE;ALUMINUM FLUORIDE [MI];ALUMINUM FLUORIDE [HSDB];ALUMINUM FLUORIDE [INCI];Aluminium(III) fluoride, anhydrous;AMY37021;Aluminum fluoride, anhydrous, 99+%;PC1008;AKOS024438230;AKOS025310871;Aluminum, di-.mu.-fluorotetrafluorodi-;Zinc Telluride (ZnTe) Sputtering Targets;A839240

Chemical Property of Aluminium fluoride

Chemical Property:

• Appearance/Colour: white crystalline powder, odorless
• Melting Point: 250 °C
• Boiling Point: 19.5 °C at 760 mmHg
• Flash Point: 1250 °C
• PSA: 0.00000
• Density: 3.1 g/mL at 25 °C(lit.)
• LogP: -8.65050
• Water Solubility.: SLIGHTLY SOLUBLE
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 83.9767479
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: T:toxic
• Statements: R36/37/38:
• Safety Statements: S26:; S37/39:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [F-].[F-].[F-].[Al+3]

Technology Process of Aluminium fluoride

There total 167 articles about Aluminium fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

nitrogen trifluoride (7783-54-2) + zeolite H-SSZ-32 → aluminum(III) fluoride (7784-18-1)

Guidance literature:

In neat (no solvent); plasma react. in inductively coupled tubular reactor, temp. of reactor exterior <=180°C, 200 mg of powdered precursor in alumina boat, power of 150-200 W, chamber pressure of 250 mTorr, NF3 flow rate of 10 sccm, reaction time of 10-20 min; X-ray diffraction anal.; EDX anal.; chem. anal.;

DOI:10.1021/ja015645t

Reference yield: 94.0%

sodium tetrahydroborate (16940-66-2) + aluminium trichloride (7446-70-0) + BF3-triglymate → aluminum(III) fluoride (7784-18-1) + sodium chloride (7647-14-5) + diborane (19287-45-7)

Guidance literature:

In further solvent(s); soln. NaBH4 in triglyme was added slowly for 2-3 h at room temp. to BF3-triglyme, AlCl3 in triglyme; B2H6 was absorbed with THF;

DOI:10.1021/ic0000911

Reference yield: 94.0%

sodium tetrahydroborate (16940-66-2) + aluminium trichloride (7446-70-0) + BF3-tetraglymate → aluminum(III) fluoride (7784-18-1) + sodium chloride (7647-14-5) + diborane (19287-45-7)

Guidance literature:

In further solvent(s); soln. NaBH4 in triglyme was added slowly for 2-3 h at room temp. to BF3-tetraglyme, AlCl3 in triglyme; B2H6 was absorbed with THF;

DOI:10.1021/ic0000911

upstream raw materials:

Chlorotrifluoroethylene

aluminium

aluminum oxide

trifluoromethan

Downstream raw materials:

aluminium

0.1AlF₃*F_0.9Na_0.9

0.26AlF₃*F_0.74Na_0.74

0.4AlF₃*F_0.6Na_0.6

Refernces

• 1、 Sun, Yang-Kook,Myung, Seung-Taek,Park, Byung-Chon,Yashiro, Hitoshi. "Improvement of the electrochemical properties of Li [Ni0.5 Mn0.5] O2 by AlF3 coating". . p. A705-A710. Retrieved 2008.
• 2、 Delattre,Chupas,Grey,Stacy. "Plasma-fluorination synthesis of high surface area aluminum trifluoride from a zeolite precursor [9]". . p. 5364 - 5365. Retrieved 2001.
• 3、 Abdel-Rehim. "Thermal and XRD analysis of synthesis of fluoro-topaz". . p. 29 - 35. Retrieved 2012.
• 4、 Daniel, Ph.,Bulou, A.,Rousseau, M.,Nouet, J.,Fourquet, J. L.,et al.. "". . . Retrieved 1990.
• 5、 McVicker, G. B.,Kim, C. J.,Eggert, J. J.. "". . p. 315 - 327. Retrieved 1983.
• 6、 Gauthier, S.,Cheveigne, S. De,Salace, G.,Klein, J.,Belin, M.. "". . p. 31 - 45. Retrieved 1985.
• 7、 Wang, Rui,Zhou, Ji,Li, Bo,Li, Longtu. "CaF2-AlF3-SiO2 glass-ceramic with low dielectric constant for LTCC application". . p. 204 - 207. Retrieved 2010.
• 8、 Feist,K?nig,B??ler,Kemnitz. "Adsorption properties of various forms of aluminium trifluoride investigated by PulseTA". . p. 100 - 105. Retrieved 2010.
• 9、 Aghalte,Omanwar,Moharil. "Luminescence characteristics of LiCaAlF6: Eu phosphor". . p. 1561 - 1566. Retrieved 2007.
• 10、 Quan,Ge,Li,Yin,Zhong,Hao,Li,Ji. "Desorption behaviour of HF,HCFC-133a and HFC-134a on a catalyst supported on γ-AlF3". . p. 213 - 220. Retrieved 1999.