Perchloromethyl mercaptan

Base Information Edit

Chemical Name:Perchloromethyl mercaptan
CAS No.:594-42-3
Deprecated CAS:20434-91-7,75-70-7,344328-67-2,344328-67-2,75-70-7
Molecular Formula:CCl4 S
Molecular Weight:185.889
Hs Code.:2930909090
European Community (EC) Number:209-840-4
ICSC Number:0311
NSC Number:66404
UN Number:1670
UNII:KK489OII9M
DSSTox Substance ID:DTXSID6025854
Nikkaji Number:J6.775J
Wikipedia:Perchloromethyl_mercaptan
Wikidata:Q680191
ChEMBL ID:CHEMBL3188766
Mol file:594-42-3.mol

Synonyms:perchloromethyl mercaptan;trichloromethylsulfenyl chloride

Suppliers and Price of Perchloromethyl mercaptan

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
PerchloromethylMercaptan
25g
$ 95.00

Sigma-Aldrich
Trichloromethanesulfenyl chloride ≥96%
25g
$ 101.00

Medical Isotopes, Inc.
PerchloromethylMercaptan
100 g
$ 830.00

Medical Isotopes, Inc.
PerchloromethylMercaptan
25 g
$ 610.00

Total 3 raw suppliers

Chemical Property of Perchloromethyl mercaptan Edit

Chemical Property:

Appearance/Colour:A yellow oily liquid with an offensive odor.
Vapor Pressure:2.02 psi ( 20 °C)
Melting Point:-44oC
Refractive Index:n20/D 1.537(lit.)
Boiling Point:146-148 ºC
PSA：25.30000
Density:1.7
LogP:3.20110
Storage Temp.:-20°C Freezer
Solubility.:Chloroform, Ethyl Acetate
XLogP3:3.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:185.844532
Heavy Atom Count:6
Complexity:37.3
Transport DOT Label:Poison Inhalation Hazard

Purity/Quality:

97% ^*data from raw suppliers

PerchloromethylMercaptan ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:T,T+,N
Statements: 23/24/25-34-26-25-21-52/53
Safety Statements: 26-36/37/39-45-7/9-28A-25-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Chemical Classes:Toxic Gases & Vapors -> Other Toxic Gases & Vapors
Canonical SMILES:C(SCl)(Cl)(Cl)Cl
Inhalation Risk:A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20 °C.
Effects of Short Term Exposure:The substance is severely irritating to the eyes, skin and respiratory tract. Inhalation of high concentrations of the vapour may cause lung oedema. Exposure above the OEL could cause death. The effects may be delayed. Medical observation is indicated.
Uses Organic synthesis, dye intermediate, fumigant. Production of fungicides; vulcanizing accelerator in rubber industry Perchloromethyl Mercaptan is used as a reactant in the preparation of thio- and selenoesters of triflic acid via a route to thio- and selenosulfonates from disulfides and diselenides.

Technology Process of Perchloromethyl mercaptan

There total 30 articles about Perchloromethyl mercaptan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.5%

: 67-66-3,8013-54-5
chloroform

: 594-42-3
chlorothio-trichloro-methane

Guidance literature:: With sulfur dichloride; triethylamine; at 10 ℃; for 5h; Time; Temperature; Reagent/catalyst;

Reference yield: 83.0%

: 74128-90-8
2,2,2',2'-Tetrachlor-1,1'-diphenyl-2,2'-trithiobis(ethanon)

: 98-86-2
acetophenone

: 98-88-4
benzoyl chloride

: 594-42-3
chlorothio-trichloro-methane

Guidance literature:: acetophenone; With pyridine; thionyl chloride; at 75 ℃; for 6.5h;

2,2,2',2'-Tetrachlor-1,1'-diphenyl-2,2'-trithiobis(ethanon); In neat (no solvent); at 140 ℃; for 15h;
DOI:10.1021/acs.joc.5b01707