Methyl 4,6-dichloropicolinate

Base Information

Chemical Name:Methyl 4,6-dichloropicolinate
CAS No.:98273-19-9
Molecular Formula:C7H5Cl2NO2
Molecular Weight:206.028
Hs Code.:2933399090
European Community (EC) Number:807-073-5
DSSTox Substance ID:DTXSID70596506
Wikidata:Q82491781
Mol file:98273-19-9.mol

Synonyms:Methyl 4,6-dichloropicolinate;98273-19-9;methyl 4,6-dichloropyridine-2-carboxylate;MFCD12965121;2-Pyridinecarboxylic acid, 4,6-dichloro-, methyl ester;Methyl4,6-dichloropicolinate;SCHEMBL245102;4,6-dichloro-2-Pyridinecarboxylic acid methyl ester;methyl 4,6-dichloro-picolinate;AMY9331;DTXSID70596506;MXHPWLMQTZILLL-UHFFFAOYSA-N;2-carbomethoxy-4,6-dichloropyridine;AKOS015848848;CS-W005398;PB44001;PS-5249;4,6-dichloropicolinic acid methyl ester;4,6-dichloro picolinic acid methyl ester;SY065716;DB-080503;EN300-107993;Methyl 4,6-dichloropyridine-2-carboxylate, 97%;A849300;J-522279;4,6-Dichloro-pyridine-2-carboxylic acid methyl ester

Suppliers and Price of Methyl 4,6-dichloropicolinate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl4,6-dichloropicolinate
1g
$ 130.00

SynQuest Laboratories
Methyl 4,6-dichloropyridine-2-carboxylate
1 g
$ 71.00

SynQuest Laboratories
Methyl 4,6-dichloropyridine-2-carboxylate
250 mg
$ 37.00

Sigma-Aldrich
Methyl 4,6-dichloropyridine-2-carboxylate 97%
1g
$ 77.20

Matrix Scientific
Methyl 4,6-dichloropicolinate 95+%
5g
$ 930.00

Matrix Scientific
Methyl 4,6-dichloropicolinate 95+%
1g
$ 247.00

Frontier Specialty Chemicals
Methyl 4,6-dichloropyridine-2-carboxylate 95%
5g
$ 120.00

Frontier Specialty Chemicals
Methyl 4,6-dichloropyridine-2-carboxylate 95%
1g
$ 30.00

Crysdot
Methyl4,6-dichloropicolinate 98%
10g
$ 296.00

Crysdot
Methyl4,6-dichloropicolinate 98%
25g
$ 593.00

Total 36 raw suppliers

Chemical Property of Methyl 4,6-dichloropicolinate

Chemical Property:

Melting Point:78-82°C
Boiling Point:125 °C(Press: 2-3 Torr)
PKA:-2.97±0.10(Predicted)
PSA：39.19000
Density:1.426±0.06 g/cm3(Predicted)
LogP:2.17500
Storage Temp.:2-8°C
XLogP3:2.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:204.9697338
Heavy Atom Count:12
Complexity:177

Purity/Quality:

99%, ^*data from raw suppliers

Methyl4,6-dichloropicolinate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=NC(=CC(=C1)Cl)Cl

Technology Process of Methyl 4,6-dichloropicolinate

There total 2 articles about Methyl 4,6-dichloropicolinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 98-98-6
2-Picolinic acid

: 67-56-1
methanol

: 24484-93-3
4-Chloro-pyridine-2-carboxylic acid methyl ester

: 98273-19-9
methyl 4,6-dichloropyridine-2-carboxylate

Guidance literature:: With thionyl chloride; sodium iodide; Yield given. Multistep reaction. Yields of byproduct given; 1.) 76 h, 2.) r.t., 0.5 h;
DOI:10.1080/00304949709355174

Reference yield:

: 98-98-6
2-Picolinic acid

: 67-56-1
methanol

: 2459-07-6,260998-83-2
methyl pyridine-2-carboxylate

: 98273-19-9
methyl 4,6-dichloropyridine-2-carboxylate

: 176977-85-8
methyl 4-chloropyridine-2-carboxylate hydrochloride

Guidance literature:: With thionyl chloride; N,N-dimethyl-formamide; Yield given. Multistep reaction; 1) 40-45 deg C, 45 min; 45->72 deg C, 2 h; 72 deg C, 21 h, 2) toluene, room temperature, 1 h;
DOI:10.1080/00397919608003557