Methyl 5-chloro-2-methyl-3-nitrobenzoate

Base Information

Chemical Name:Methyl 5-chloro-2-methyl-3-nitrobenzoate
CAS No.:294190-17-3
Molecular Formula:C9H8ClNO4
Molecular Weight:229.62
Hs Code.:2916399090
DSSTox Substance ID:DTXSID90694573
Wikidata:Q72489311
Mol file:294190-17-3.mol

Synonyms:Methyl 5-chloro-2-methyl-3-nitrobenzoate;294190-17-3;5-Chloro-2-methyl-3-nitro-benzoic acid methyl ester;SCHEMBL2043408;DTXSID90694573;JAMJGHLCWGZMDT-UHFFFAOYSA-N;AMY28076;MFCD11845450;AKOS016011203;Methyl5-chloro-2-methyl-3-nitrobenzoate;AC-33897;AS-30672

Suppliers and Price of Methyl 5-chloro-2-methyl-3-nitrobenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl5-Chloro-2-methyl-3-nitrobenzoate
50mg
$ 45.00

Crysdot
Methyl5-chloro-2-methyl-3-nitrobenzoate 95%
1g
$ 220.00

Crysdot
Methyl5-chloro-2-methyl-3-nitrobenzoate 95%
5g
$ 575.00

Chemcia Scientific
5-Chloro-2-methyl-3-nitro-benzoicacidmethylester ＞97%
5 G
$ 400.00

Chemcia Scientific
5-Chloro-2-methyl-3-nitro-benzoicacidmethylester ＞97%
1 G
$ 130.00

American Custom Chemicals Corporation
5-CHLORO-2-METHYL-3-NITRO-BENZOIC ACID METHYL ESTER 95.00%
250MG
$ 194.25

Alichem
Methyl5-chloro-2-methyl-3-nitrobenzoate
500mg
$ 863.90

Alichem
Methyl5-chloro-2-methyl-3-nitrobenzoate
250mg
$ 499.20

Total 28 raw suppliers

Chemical Property of Methyl 5-chloro-2-methyl-3-nitrobenzoate

Chemical Property:

Boiling Point:317.1±37.0 °C(Predicted)
PSA：72.12000
Density:1.371±0.06 g/cm3(Predicted)
LogP:2.86640
Storage Temp.:Sealed in dry,Room Temperature
XLogP3:2.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:229.0141854
Heavy Atom Count:15
Complexity:265

Purity/Quality:

99%, ^*data from raw suppliers

Methyl5-Chloro-2-methyl-3-nitrobenzoate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=C(C=C(C=C1[N+](=O)[O-])Cl)C(=O)OC

Technology Process of Methyl 5-chloro-2-methyl-3-nitrobenzoate

There total 4 articles about Methyl 5-chloro-2-methyl-3-nitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 154257-81-5
5-chloro-2-methyl-3-nitrobenzoic acid

: 74-88-4
methyl iodide

: 294190-17-3
methyl 5-chloro-2-methyl-3-nitrobenzoate

Guidance literature:: With sodium carbonate; In N,N-dimethyl-formamide; at 60 ℃; for 4h; Product distribution / selectivity;

Reference yield: 69.2%

: 67-56-1
methanol

: 154257-81-5
5-chloro-2-methyl-3-nitrobenzoic acid

: 294190-17-3
methyl 5-chloro-2-methyl-3-nitrobenzoate

Guidance literature:: methanol; With thionyl chloride; at 0 ℃; for 0.25h;

5-chloro-2-methyl-3-nitrobenzoic acid; at 20 ℃; for 24h;

Reference yield:

: 7499-06-1
5-chloro-2-methylbenzoic acid

: 294190-17-3
methyl 5-chloro-2-methyl-3-nitrobenzoate

Guidance literature:: Multi-step reaction with 2 steps

1: sulfuric acid / nitric acid / 3.5 h / -5 - 0 °C

2: sulfuric acid / 16 h / 0 °C / Reflux

With sulfuric acid; nitric acid;