ethyl (6-methoxy-1-oxo-1,2,3,4-tetrahydronaphthalen-2-yl)acetate

Base Information

Chemical Name:ethyl (6-methoxy-1-oxo-1,2,3,4-tetrahydronaphthalen-2-yl)acetate
CAS No.:50558-96-8
Molecular Formula:C₁₅H₁₈O₄
Molecular Weight:262.306
Hs Code.:
Mol file:50558-96-8.mol

Synonyms:2-Naphthaleneacetic acid, 1,2,3,4-tetrahydro-6-methoxy-1-oxo-, ethyl ester

Suppliers and Price of ethyl (6-methoxy-1-oxo-1,2,3,4-tetrahydronaphthalen-2-yl)acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 3 raw suppliers

Chemical Property of ethyl (6-methoxy-1-oxo-1,2,3,4-tetrahydronaphthalen-2-yl)acetate

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Boiling Point:402.251°C at 760 mmHg
Flash Point:178.188°C
Density:1.136g/cm³

Purity/Quality:: 99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

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Technology Process of ethyl (6-methoxy-1-oxo-1,2,3,4-tetrahydronaphthalen-2-yl)acetate

There total 5 articles about ethyl (6-methoxy-1-oxo-1,2,3,4-tetrahydronaphthalen-2-yl)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 64-17-5
ethanol

: 17529-16-7
6-methoxy-1-oxo-1,2,3,4-tetrahydronaphthalene-2-acetic acid

: 50558-96-8
6-methoxy-1,2,3,4-tetrahydro-1-oxonaphthalene-2-acetic acid, ethyl ester

Guidance literature:: With methanesulfonic acid; at 20 ℃; for 16h;

Reference yield: 56.0%

: 105-36-2
ethyl bromoacetate

: 1078-19-9
6-methoxy-3,4-dihydro-1(2H)-naphthalenone

: 50558-96-8
6-methoxy-1,2,3,4-tetrahydro-1-oxonaphthalene-2-acetic acid, ethyl ester

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; hexane; at -60 - 20 ℃; for 16h;
DOI:10.1021/jm00113a014

Reference yield:

: 1078-19-9
6-methoxy-3,4-dihydro-1(2H)-naphthalenone

: 50558-96-8
6-methoxy-1,2,3,4-tetrahydro-1-oxonaphthalene-2-acetic acid, ethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: sulfuric acid / water; diethylene glycol dimethyl ether / 110 °C

2: acetic acid; zinc / water / 3 h / 100 °C

3: methanesulfonic acid / 16 h / 20 °C

With methanesulfonic acid; sulfuric acid; acetic acid; zinc; In diethylene glycol dimethyl ether; water;