Methyl 2-O,3-O,4-O-tris(trimethylsilyl)-6-deoxy-α-L-mannopyranoside

Base Information

Chemical Name:Methyl 2-O,3-O,4-O-tris(trimethylsilyl)-6-deoxy-α-L-mannopyranoside
CAS No.:56271-60-4
Molecular Formula:
Molecular Weight:394.73
Hs Code.:
Mol file:56271-60-4.mol

Synonyms:Methyl 2-O,3-O,4-O-tris(trimethylsilyl)-6-deoxy-α-L-mannopyranoside

Suppliers and Price of Methyl 2-O,3-O,4-O-tris(trimethylsilyl)-6-deoxy-α-L-mannopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 3 raw suppliers

Chemical Property of Methyl 2-O,3-O,4-O-tris(trimethylsilyl)-6-deoxy-α-L-mannopyranoside

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Methyl 2-O,3-O,4-O-tris(trimethylsilyl)-6-deoxy-α-L-mannopyranoside

There total 10 articles about Methyl 2-O,3-O,4-O-tris(trimethylsilyl)-6-deoxy-α-L-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 67-56-1
methanol

: 75-77-4
chloro-trimethyl-silane

[GlcA-Rha]27[IdoA-Rha]6[GlcA-Rha-Xyl]7GlcA₉Glc₄[SO₃-]26: [GlcA-Rha]27[IdoA-Rha]6[GlcA-Rha-Xyl]7GlcA₉Glc₄[SO₃-]26

: 25561-30-2
N,O-Bis(trimethylsilyl)trifluoroacetamide

: C₁₃H₂₆O₆Si₂

: 3370-86-3
methyl 2,3,4-tri-O-(trimethylsilyl)-α/β-D-xylopyranoside

: 109100-61-0
O¹-methyl-O²,O⁵-bis-trimethylsilanyl-β-D-glucofuranuronic acid-lactone

: 1769-06-8,2296-39-1,2296-40-4,2641-79-4,3504-67-4,3504-69-6,3504-70-9,3504-71-0,3504-73-2,4002-00-0,4133-45-3,83946-62-7,83946-63-8,83946-64-9
methyl 2,3,4,6-tetrakis-O-(trimethylsilyl)-α/β-D-glucopyranoside

: 56271-60-4,56271-59-1
(3R,4R,5S,6S)-2-Methoxy-6-methyl-3,4,5-tris-trimethylsilanyloxy-tetrahydro-pyran

: C₁₉H₄₄O₇Si₄

Guidance literature:: methanol; [GlcA-Rha]27[IdoA-Rha]6[GlcA-Rha-Xyl]7GlcA₉Glc₄[SO₃-]26; With hydrogenchloride; at 100 ℃; for 4h;

chloro-trimethyl-silane; N,O-Bis(trimethylsilyl)trifluoroacetamide; With pyridine; at 80 ℃; for 0.5h;
DOI:10.1016/j.carbpol.2011.12.041

Reference yield:

: 182818-70-8
1-(methoxycarbonyl)pentadec-10(S)-yl α-L-rhamnopyranoside

: 56271-60-4,56271-59-1
(3R,4R,5S,6S)-2-Methoxy-6-methyl-3,4,5-tris-trimethylsilanyloxy-tetrahydro-pyran

Guidance literature:: Multi-step reaction with 12 steps

1: 214 mg / (1R)-(-)-10-camphorsulfonic acid / dimethylformamide / 3 h / Ambient temperature

2: 620 mg / BF₃*Et₂O, 4 A molecular sieves / CH₂Cl₂ / 4 h / -40 °C

3: 152 mg / 10percent NaOMe / methanol / 0.5 h / Ambient temperature

4: 148 mg / (1R)-(-)-10-camphorsulfonic acid / dimethylformamide / 2 h / Ambient temperature

5: 210 mg / BF₃*Et₂O, 4 A molecular sieves / CH₂Cl₂ / 2 h / -40 °C

6: 108 mg / 10percent NaOMe / methanol / 0.5 h / Ambient temperature

7: 72 mg / (1R)-(-)-10-camphorsulfonic acid / dimethylformamide / 2 h / Ambient temperature

8: 85 mg / BF₃*Et₂O, 4 A molecular sieves / CH₂Cl₂ / 2 h / -40 °C

9: 72 mg / 2percent NaOMe / methanol / 0.33 h / Ambient temperature

10: 7.0 mg / 1percent HCl / methanol / 2 h / Ambient temperature

11: 18 mg / 9percent HCl, MeOH / 1 h / Heating

12: pyridine / 1 h / Ambient temperature

With pyridine; hydrogenchloride; methanol; 4 A molecular sieve; boron trifluoride diethyl etherate; (R)-10-camphorsulfonic acid; sodium methylate; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1248/cpb.44.1680

Reference yield:

: 115655-84-0
1-(methoxycarbonyl)pentadec-10(S)-yl 2,3-O-isopropylidene-α-L-rhamnopyranoside

: 56271-60-4,56271-59-1
(3R,4R,5S,6S)-2-Methoxy-6-methyl-3,4,5-tris-trimethylsilanyloxy-tetrahydro-pyran

Guidance literature:: Multi-step reaction with 11 steps

1: 620 mg / BF₃*Et₂O, 4 A molecular sieves / CH₂Cl₂ / 4 h / -40 °C

2: 152 mg / 10percent NaOMe / methanol / 0.5 h / Ambient temperature

3: 148 mg / (1R)-(-)-10-camphorsulfonic acid / dimethylformamide / 2 h / Ambient temperature

4: 210 mg / BF₃*Et₂O, 4 A molecular sieves / CH₂Cl₂ / 2 h / -40 °C

5: 108 mg / 10percent NaOMe / methanol / 0.5 h / Ambient temperature

6: 72 mg / (1R)-(-)-10-camphorsulfonic acid / dimethylformamide / 2 h / Ambient temperature

7: 85 mg / BF₃*Et₂O, 4 A molecular sieves / CH₂Cl₂ / 2 h / -40 °C

8: 72 mg / 2percent NaOMe / methanol / 0.33 h / Ambient temperature

9: 7.0 mg / 1percent HCl / methanol / 2 h / Ambient temperature

10: 18 mg / 9percent HCl, MeOH / 1 h / Heating

11: pyridine / 1 h / Ambient temperature

With pyridine; hydrogenchloride; methanol; 4 A molecular sieve; boron trifluoride diethyl etherate; (R)-10-camphorsulfonic acid; sodium methylate; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1248/cpb.44.1680