(CH3)2NCH2Si(CH3)3

Base Information

• Chemical Name: (CH3)2NCH2Si(CH3)3
• CAS No.: 18182-40-6
• Molecular Formula: C6H17 N Si
• Molecular Weight: 131.293
• Hs Code.: 2931900090
• Mol file: 18182-40-6.mol

Synonyms:Trimethylamine,(trimethylsilyl)- (8CI); (Trimethylsilylmethyl)dimethylamine; NSC 93027;Trimethyl(dimethylaminomethyl)silane; [(Dimethylamino)methyl]trimethylsilane

Chemical Property of (CH3)2NCH2Si(CH3)3

Chemical Property:

• Vapor Pressure: 69.7mmHg at 25°C
• Boiling Point: 85.3°Cat760mmHg
• Flash Point: 5.4°C
• PSA: 3.24000
• Density: 0.769g/cm³
• LogP: 1.84370

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (CH3)2NCH2Si(CH3)3

There total 8 articles about (CH3)2NCH2Si(CH3)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 18.0%

{2-(trimethylgermyl)-2-(trimethylsilyl)ethyl}trimethylammonium iodide (125069-59-2) → (N,N-dimethylaminomethyl)trimethylgermane (21673-26-7) + N-(trimethylsilylmethyl)dimethylamine (18182-40-6)

Guidance literature:

With n-butyllithium; In N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; under N2, dropwise addn. of soln. of n-C4H9Li to soln. of amine, -20°C, stirring, 2 h; pouring reaction mixt. into chilled H2O, extg. with Et2O; products identified by GC;

DOI:10.1016/0022-328X(89)88037-4

Reference yield: 11.0%

{2-(trimethylgermyl)-2-(trimethylsilyl)ethyl}trimethylammonium iodide (125069-59-2) + lithium diisopropyl amide (4111-54-0) → (N,N-dimethylaminomethyl)trimethylgermane (21673-26-7) + N-(trimethylsilylmethyl)dimethylamine (18182-40-6) + 1-(trimethylgermyl)-1-(trimethylsilyl)ethylene (2290-60-0)

Guidance literature:

In N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; under N2, dropwise addn. of soln. of LDA to soln. of amine, -20°C, stirring, 2 h; pouring reaction mixt. into chilled H2O, extg. with Et2O, washing with 5% HCl, H2O, satd. aq. NaCl, drying (MgSO4), concg., distn. in vac.; products identified by GC;

DOI:10.1016/0022-328X(89)88037-4

Reference yield: 7.0%

Benzyldimethyl<(trimethylsilyl)methyl>ammonium bromide (72443-52-8) → N,N'-dimethylbenzylamine (103-83-3) + N-(trimethylsilylmethyl)dimethylamine (18182-40-6) + N-benzyl-N-methyl-1-(trimethylsilyl)methanamine (51951-99-6) + N,N-dimethyl(2-methylbenzyl)amine (4525-48-8)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; for 10h; Yield given; Heating;

DOI:10.1021/jo01292a011

upstream raw materials:

dimethyl amine

Chloromethyltrimethylsilane

chloro-trimethyl-silane

dimethylaminomethyltributyltin

Downstream raw materials:

N-Methyl-N-(-1-trimethylsilylaethyl)-anilin

Dimethyl-(3-methyl-benzyl)-trimethylsilanylmethyl-ammonium; bromide

(4-Acetoxy-benzyl)-dimethyl-trimethylsilanylmethyl-ammonium; bromide

dimethyl<4-(tert-butoxycarbonyl)benzyl><(trimethylsilyl)methyl>ammonium bromide