9-Cl-o-HCB₁₀H₉CH

Base Information

• Chemical Name: 9-Cl-o-HCB₁₀H₉CH
• CAS No.: 19513-12-3
• Molecular Formula: C₂H₁₁B₁₀Cl
• Molecular Weight: 178.672
• Mol file: 19513-12-3.mol

Synonyms:9-Cl-o-HCB₁₀H₉CH

Chemical Property of 9-Cl-o-HCB₁₀H₉CH

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of 9-Cl-o-HCB₁₀H₉CH

There total 2 articles about 9-Cl-o-HCB₁₀H₉CH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

9-chloro-m-carborane (17819-85-1) → 3-amino-1,2-dicarbaborane (22043-65-8) + 1,2-dicarba-closo-dodecaborane(12) (16872-09-6) + 1,7-dicarba-closo-dodecaborane(12) (16986-24-6) + 9-Cl-o-HCB10H9CH (19513-12-3)

Guidance literature:

With potassium permanganate; sodium; In ammonia; redn. with 2 equival. Na in liq. NH3, oxidn. with KMnO4;; 5% m-carborane, 10% o-carborane, 23% 9-Cl-o-carborane, 15% 3-amino-o-carborane;;

Reference yield:

aluminium trichloride (7446-70-0) + 1,2-dicarba-closo-dodecaborane(12) (16872-09-6) + iodine (7553-56-2,12190-71-5,8031-47-8) → 9-iodo-o-carborane (17830-03-4) + 9-Cl-o-HCB10H9CH (19513-12-3) + 9,12-diiodo-1,2-dicarba-closo-dodecarborane(12) (17702-35-1) + 9.12-Cl2-1.2-C2B10H10 (19511-39-8) + 9-chloro-12-iodo-o-carborane (98330-59-7)

Guidance literature:

In tetrachloromethane; refluxing soln. of I2, o-carborane and AlCl3 in CCl4 under N2 for 3 h;; pouring into distd. water; separation of organic layer; drying over MgSO4; filtration; concentrating; product mixt. obtained; gas chromatography; separation by preparative gas chromatography; elem. anal.; mass spectroscopy; NMR spectroscopy;;

Reference yield:

9-Cl-o-HCB10H9CH (19513-12-3) → 3-amino-1,2-dicarbaborane (22043-65-8) + 1,2-dicarba-closo-dodecaborane(12) (16872-09-6)

Guidance literature:

With potassium permanganate; sodium; In ammonia; redn. with 2 equival. Na in liq. NH3, oxidn. with KMnO4;; 27% o-carborane, 20% 3-amino-o-carborane;;

upstream raw materials:

9-chloro-m-carborane

aluminium trichloride

1,2-dicarba-closo-dodecaborane⁽¹²⁾

iodine

Downstream raw materials:

1,2-dicarba-closo-dodecaborane⁽¹²⁾

3-amino-1,2-dicarbaborane

Refernces