chloro(4-methoxyphenyl)mercury

Base Information

• Chemical Name: chloro(4-methoxyphenyl)mercury
• CAS No.: 3009-79-8
• Molecular Formula: C7H7 Cl Hg O
• Molecular Weight: 343.175
• Mol file: 3009-79-8.mol

Synonyms:(p-Methoxyphenyl)mercurychloride (6CI); Mercury, chloro(p-methoxyphenyl)- (7CI,8CI); Benzene, methoxy-,mercury complex; (4-Methoxyphenyl)mercuric chloride; (p-Methoxyphenyl)mercuricchloride; 4-Anisylmercuric chloride; Chloro(4-methoxyphenyl)mercury;Chloro(p-methoxyphenyl)mercury; NSC 16239; p-(Chloromercuri)anisole;p-Anisylchloromercury; p-Anisylmercuric chloride

Chemical Property of chloro(4-methoxyphenyl)mercury

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of chloro(4-methoxyphenyl)mercury

There total 6 articles about chloro(4-methoxyphenyl)mercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

[(C5H5)2Ti(C6H4OCH3)(CH3)] (86822-34-6) + mercury dichloride → bis(cyclopentadienyl)methyltitanium(IV) chloride (1278-83-7) + [(C5H5)2TiCl(C6H4OCH3)] (86822-33-5) + methylmercury(II) chloride (115-09-3) + p-anisylmercuric chloride (3009-79-8)

Guidance literature:

In [⁽²⁾H₆]acetone; to cold (-78 °C) soln. of Ti complex in acetone-d6 added soln. of HgCl2 in acetone-d6 under N2; warmed to room temp., monitored by NMR;

DOI:10.1021/om50004a026

Reference yield: 66.0%

4-methoxyphenyl magnesium bromide (13139-86-1) + mercury dichloride → p-anisylmercuric chloride (3009-79-8)

Guidance literature:

In diethyl ether; refluxing 2.5 h, then stirring overnight, ppn. with KCl/HCl conc./H2O; recrystn. (1,4-dioxane);

DOI:10.1021/ja00324a029

Reference yield: 65.0%

mercury(II) diacetate (1600-27-7) + methoxybenzene (100-66-3) + sodium chloride (7647-14-5) → p-anisylmercuric chloride (3009-79-8)

Guidance literature:

In water; N,N-dimethyl-formamide; other Radiation; microwave oven (2450 MHz, 1.5 min); evapn. (vac.), water addn., washing (water), drying, recrystn. (acetone);

DOI:10.1016/0277-5387(95)00569-2

upstream raw materials:

4-methoxyphenylboronic acid

4,4'-dimethoxy-diphenyliodonium chloride

[(C₅H₅)2Ti(C₆H₄OCH₃)(CH₃)]

mercury(II) diacetate

Downstream raw materials:

β-4-methoxyphenyl-β-methylstyrene

phenyl(p-methoxyphenyl)tellurium dichloride

1-cyclooctyl-4-methoxybenzene

4-Methoxy-4'-phenyl-stilben