Triphenylantimony oxide

Base Information

• Chemical Name: Triphenylantimony oxide
• CAS No.: 4756-75-6
• Molecular Formula: C18H15OSb
• Molecular Weight: 369.067
• European Community (EC) Number: 225-292-9
• NSC Number: 99161
• DSSTox Substance ID: DTXSID30197199
• Wikidata: Q83070147
• Mol file: 4756-75-6.mol

Synonyms:Triphenylantimony oxide;4756-75-6;Triphenylstibine oxide;diphenylstiborylbenzene;Stibine oxide, triphenyl-;Triphenylantimonyoxide;EINECS 225-292-9;NSC 99161;BRN 4136903;AI3-52760;Stibine oxide, triphenyl-, hydrate;Triphenyl antimony oxide;triphenylantimony(V) oxide;C18H15OSb;SCHEMBL3798023;C18-H15-O-Sb;DTXSID30197199;NSC99161;MFCD00013837;NSC-99161;AKOS015840470;LS-146733;CS-0086386;FT-0635431;T72508

Chemical Property of Triphenylantimony oxide

Chemical Property:

• PSA: 17.07000
• LogP: 4.34160
• Storage Temp.: Refrigerator
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 368.01610
• Heavy Atom Count: 20
• Complexity: 281

Purity/Quality:

98%,99%, ^*data from raw suppliers

Triphenylantimony Oxide >95.0%(HPLC) ^*data from reagent suppliers

Safty Information:

• Statements: 20/22-51/53
• Safety Statements: 22-36/37/39

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sb](=O)(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of Triphenylantimony oxide

There total 13 articles about Triphenylantimony oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

tetraphenylstibonium hydroxide (13371-35-2,19638-16-5) → triphenyl antimony oxide (4756-75-6) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

In chlorobenzene; byproducts: benzene; stirring soln. under Ar for 48 h at 110°C; distn. of solvent, G.C.anal. of benzene;

Reference yield: 99.0%

tris(2-methoxyphenyl)bismuthane oxide + triphenylantimony (603-36-1) → tris(2-methoxyphenyl)bismuthine (83724-41-8) + triphenyl antimony oxide (4756-75-6)

Guidance literature:

In dichloromethane; Ph3Sb (2 equiv.) added to CH2Cl2 soln. of Bi compd. at room temp.; reacted for 30 min; concd. under reduced pressure; detd. by (1)H NMR spectra;

DOI:10.1021/om0494115

Reference yield: 94.0%

triphenylantimony (603-36-1) → triphenyl antimony oxide (4756-75-6)

Guidance literature:

With t-butyl hydroperoxide or cumyl hydroperoxide; In benzene; 40 to 50°C, equimolar amts.;

upstream raw materials:

dihydrogen peroxide

triphenylantimony

tetraphenylantimony phthalate

tert.-butylhydroperoxide

Downstream raw materials:

(C₆H₅)3Sb(O₂CCH₂-2-C₄H₃O)2

(C₆H₅)3Sb(O₂CCH₂-2-C₄H₃S)2

triphenylantimony bis(2-furoinate)

(C₆H₅)3Sb(O₂C-2-C₄H₃S)2

Refernces

• 1、 El-Sayed, Naglaa F.,Ewies, Ewies F.,El-Hussieny, Marwa,Boulos, Leila S.,Shalaby, ElSayed M.. "Synthesis of novel pyrazole derivatives using organophosphorus, stibine, and arsine reagents and their antitumor activities". . p. 765 - 776. Retrieved 2016/07/27.
• 2、 Sharutin,Sharutina,Osipov,Zhidkov,Muslin. "Thermal Decomposition of Tetraphenylstibonium Derivatives Ph4SbOR". . p. 973 - 974. Retrieved 2007/10/03.