p-nitrobenzoic acetic anhydride

Base Information

• Chemical Name: p-nitrobenzoic acetic anhydride
• CAS No.: 75474-03-2
• Molecular Formula: C₉H₇NO₅
• Molecular Weight: 209.158
• Mol file: 75474-03-2.mol

Synonyms:p-nitrobenzoic acetic anhydride

Chemical Property of p-nitrobenzoic acetic anhydride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of p-nitrobenzoic acetic anhydride

There total 5 articles about p-nitrobenzoic acetic anhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

potassium acetate (127-08-2) + 4-nitro-benzoyl chloride (122-04-3) → p-nitrobenzoic acetic anhydride (75474-03-2)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; for 0.0666667h;

DOI:10.1081/SCC-120001504

Reference yield: 97.0%

potassium 4-nitrobenzoate (15922-01-7) + acetyl chloride (75-36-5) → p-nitrobenzoic acetic anhydride (75474-03-2)

Guidance literature:

With N-benzyl-N,N,N-triethylammonium chloride; In chloroform; at 20 ℃; for 2h;

Reference yield: 65.0%

carbon monoxide (201230-82-2) + sodium acetate (127-09-3) + 4-nitrobenzenediazonium tetrafluoroborate (456-27-9) → p-nitrobenzoic acetic anhydride (75474-03-2)

Guidance literature:

palladium diacetate; In acetonitrile; for 0.5h; under 6619.6 Torr; Ambient temperature;

DOI:10.1016/S0040-4039(00)78632-1 DOI:10.1021/jo00335a018

upstream raw materials:

carbon monoxide

sodium acetate

4-nitrobenzenediazonium tetrafluoroborate

potassium acetate

Downstream raw materials:

1-(3,4-dimethoxyphenyl)ethanone

Acetanilid

p-nitrobenzoic anhydride

acetic anhydride

Refernces

• 1、 Arai, Shigeru,Sudo, Yukinori,Nishida, Atsushi. "Niobium pentachloride-silver perchlorate as an efficient catalyst in the Friedel-Crafts acylation and Sakurai-Hosomi reaction of acetals". . p. 4639 - 4642. Retrieved 2007/10/03.
• 2、 Kikukawa, Kiyoshi,Kono, Kiyoshi,Nagira, Kazuhiko,Wada, Fumio,Matsuda, Tsutomu. "Reaction of Diazonium Salts with Transition Metals. 6. Preparation of Mixed Acid Anhydrides from Arenediazonium Salts and Sodium Carboxylates under Palladium(0) Catalysis". . p. 4413 - 4416. Retrieved 2007/10/02.