Dipropylamine

Base Information

• Chemical Name: Dipropylamine
• CAS No.: 142-84-7
• Molecular Formula: C6H15N
• Molecular Weight: 101.192
• Hs Code.: 29211910
• European Community (EC) Number: 205-565-9
• UN Number: 2383
• UNII: 60P318IIRY
• DSSTox Substance ID: DTXSID2025185
• Nikkaji Number: J2.547J
• Wikipedia: Dipropylamine
• Wikidata: Q410621
• ChEMBL ID: CHEMBL3185961
• Mol file: 142-84-7.mol

Synonyms:DIPROPYLAMINE;142-84-7;Di-n-propylamine;n-Dipropylamine;N-propylpropan-1-amine;1-Propanamine, N-propyl-;N-Propyl-1-propanamine;RCRA waste number U110;RCRA waste no. U110;di(n-propyl)amine;CCRIS 4805;DIPROPYL-AMINE;HSDB 2644;EINECS 205-565-9;UN2383;BRN 0505974;UNII-60P318IIRY;AI3-24037;di-n-propylamin;60P318IIRY;DTXSID2025185;EC 205-565-9;dipropyl amine;Dipropanamina;Dipropilamina;di-propylamine;N-dipropilamina;Di-n-propilamina;di-n-propyl amine;N,N-Dipropylamine;N, N-dipropilamina;N, N-dipropilamine;N-propyl propylamine;N-propyl-propylamine;MFCD00009362;Dipropylamine, 99%;N,N-Dipropylamine #;N,N-di-n-propylamine;DNA (CHRIS Code);N-Propil-1-propanamina;1-propanamina, N-propil-;DiPropylamine Reagent Grade;DIPROPYLAMINE [HSDB];SCHEMBL15445;N-DIPROPYLAMINE [MI];(n-C3H7)2NH;DTXCID105185;CHEMBL3185961;STR03559;Tox21_202085;BBL027756;LS-841;NA2383;STL194269;AKOS000118843;UN 2383;NCGC00249163-01;NCGC00259634-01;CAS-142-84-7;D0930;Dipropylamine [UN2383] [Flammable liquid];FT-0614098;FT-0625300;Dipropylamine [UN2383] [Flammable liquid];EN300-19590;Q410621;J-007705;J-520390;F2190-0303

Chemical Property of Dipropylamine

Chemical Property:

• Appearance/Colour: clear, colorless liquid
• Vapor Pressure: 25.5mmHg at 25°C
• Melting Point: -63 °C
• Refractive Index: n20/D 1.4049(lit.)
• Boiling Point: 108.8 °C at 760 mmHg
• PKA: pK1:10.91(+1) (25°C)
• Flash Point: 3.9 °C
• PSA: 12.03000
• Density: 0.741 g/cm³
• LogP: 1.78690
• Storage Temp.: Flammables area
• Solubility.: 35g/l (experimental)
• Water Solubility.: soluble
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 101.120449483
• Heavy Atom Count: 7
• Complexity: 23.4
• Transport DOT Label: Flammable Liquid Corrosive

Purity/Quality:

99% ^*data from raw suppliers

n-Dipropylamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,C
• Hazard Codes: F,C
• Statements: 11-20/21/22-35
• Safety Statements: 16-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Nitrogen Compounds -> Amines, Aliphatic
• Canonical SMILES: CCCNCCC

Technology Process of Dipropylamine

There total 104 articles about Dipropylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

propylamine (107-10-8,42939-71-9) + ethene (74-85-1) + carbon monoxide (201230-82-2) → tri-n-propylamine (102-69-2) + di-n-propylamine (142-84-7)

Guidance literature:

di(rhodium)tetracarbonyl dichloride; In ethanol; at 119 ℃; for 1h; under 44253.5 Torr;

DOI:10.1016/0022-328X(89)87190-6

Reference yield: 89.0%

propiononitrile (107-12-0) → tri-n-propylamine (102-69-2) + N-propylidenepropylamine (7707-70-2) + di-n-propylamine (142-84-7)

Guidance literature:

With hydrogen; at 220 ℃;

DOI:10.1134/S1070427217110088

Reference yield:

propylamine (107-10-8,42939-71-9) → tri-n-propylamine (102-69-2) + isocapronitrile (542-54-1) + N-propylidenepropylamine (7707-70-2) + di-n-propylamine (142-84-7) + propiononitrile (107-12-0)

Guidance literature:

Cu-MFI/VIE; In gas; at 299.85 ℃; for 2h; Product distribution; other catalysts; var. reaction times;

DOI:10.1006/jcat.1998.2282

upstream raw materials:

propan-1-ol

propylamine

tri-n-propylamine

O-Methylhydroxylamin

Downstream raw materials:

2-(dipropylamino)ethanol

N,N-dipropylethanediamine

(2-amino-ethyl)-(2-dipropylamino-ethyl)-amine

[2-(6-methyl-[2]pyridyl)-ethyl]-dipropyl-amine

Refernces

• 1、 Annandale, Michael T.,VanLoon, Gary W.,Buncel, Erwin. "Regioselectivity and stereoelectronic effects in the reactions of the dinitroaniline herbicides trifluralin and benefin with nucleophiles". . p. 873 - 883. Retrieved 1998.
• 2、 García-Domínguez, Andrés,Gonzalez, Jorge A.,Leach, Andrew G.,Lloyd-Jones, Guy C.,Nichol, Gary S.,Taylor, Nicholas P.. "A Lewis Base Nucleofugality Parameter, NFB, and Its Application in an Analysis of MIDA-Boronate Hydrolysis Kinetics". supporting information. . Retrieved 2022/01/04.
• 3、 Rosien, Michael,T?ben, Iris,Schmidtmann, Marc,Beckhaus, Rüdiger,Doye, Sven. "Titanium-Catalyzed Hydroaminoalkylation of Ethylene". supporting information. p. 2138 - 2142. Retrieved 2020/02/05.