Cyano-(trimethylazaniumyl)boranuide

Base Information

Chemical Name:Cyano-(trimethylazaniumyl)boranuide
CAS No.:30353-61-8
Molecular Formula:C4H9BN2
Molecular Weight:0
Hs Code.:
Nikkaji Number:J1.389.150H
Mol file:30353-61-8.mol

Synonyms:

Suppliers and Price of Cyano-(trimethylazaniumyl)boranuide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
TRIMETHYLAMINE CYANOBORANE 95.00%
5MG
$ 502.00

Total 0 raw suppliers

Chemical Property of Cyano-(trimethylazaniumyl)boranuide

Chemical Property:

Vapor Pressure:1720mmHg at 25°C
Boiling Point:2.8°Cat760mmHg
Flash Point:°C
PSA：3.24000
Density:g/cm³
LogP:-0.19260
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:98.1015285
Heavy Atom Count:7
Complexity:94

Purity/Quality:: TRIMETHYLAMINE CYANOBORANE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[BH2-](C#N)[N+](C)(C)C

Technology Process of Cyano-(trimethylazaniumyl)boranuide

There total 1 articles about Cyano-(trimethylazaniumyl)boranuide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 7664-41-7
ammonia

: 25741-81-5
trimethylamine-monoiodoborane (1/1)

: 59301-48-3
ammonia-cyanoborane

: 30353-61-8
trimethylamine-cyanoborane

Guidance literature:: With sodium cyanide; In ammonia; N2-atmosphere; molar ratio borane:NaCN=1:1, stirring in excess NH3 at -44°C for 4 h; solvent removal (vac.), treatment with C6H6 for 20 min, filtration, evapn. of filtrate, sublimation (vac., 50°C);
DOI:10.1039/DT9760000353

Reference yield: 88.0%

: 30353-61-8
trimethylamine-cyanoborane

: 100-52-7
benzaldehyde

: dimethyl(2-phenyl-2-hydroxyethyl)amine cyanoborane

Guidance literature:: With sec.-butyllithium; In tetrahydrofuran; cyclohexane; (N2); soln. of s-BuLi (1.5 equiv.) in cyclohexane was added dropwise tosoln. of Me3NBH2CN in THF at -78°C; mixt. warmed to room temp. o ver 1 h; recooled to -78°C; electrophile added; after 5 min cooling bath removed; stirred for 0.5 h; aq. NaHCO3 added; org. layer septd.; washed (brine); dried (Na2SO4); filtered; concd. (vac.); ether added; stirred for 3 h; aq. NaHCO3 added; filtered; ether layer dried (Na2SO4); filtered; concd. (vac.); CH2Cl2 added; washed (H2O); extd.; elem. anal.;
DOI:10.1021/om049816p

Reference yield: 87.0%

: 30353-61-8
trimethylamine-cyanoborane

: 104-87-0
4-methyl-benzaldehyde

: 705292-56-4
dimethyl(2-p-tolyl-2-hydroxyethyl)amine cyanoborane

Guidance literature:: With sec.-butyllithium; In tetrahydrofuran; cyclohexane; (N2); soln. of s-BuLi (1.5 equiv.) in cyclohexane was added dropwise tosoln. of Me3NBH2CN in THF at -78°C; mixt. warmed to room temp. o ver 1 h; recooled to -78°C; electrophile added; after 5 min cooling bath removed; stirred for 0.5 h; aq. NaHCO3 added; org. layer septd.; washed (brine); dried (Na2SO4); filtered; concd. (vac.); ether added; stirred for 3 h; aq. NaHCO3 added; filtered; ether layer dried (Na2SO4); filtered; concd. (vac.); CH2Cl2 added; washed (H2O); extd.; elem. anal.;
DOI:10.1021/om049816p