Calo-Gran

Base Information

• Chemical Name: Calo-Gran
• CAS No.: 7546-30-7
• Molecular Formula: ClHg
• Molecular Weight: 237.051
• DSSTox Substance ID: DTXSID0020812
• Nikkaji Number: J307.833G
• Mol file: 7546-30-7.mol

Synonyms:Calo-Gran;mercury(1+) chloride;Mercurio(I) chloride;DTXSID0020812;LS-48686;104923-33-3

Chemical Property of Calo-Gran

Chemical Property:

• Appearance/Colour: dense white powder
• Vapor Pressure: 33900mmHg at 25°C
• Melting Point: 302 C
• Boiling Point: 384 C
• PSA: 0.00000
• LogP: -2.99850
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 236.939496
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Hg+]

Technology Process of Calo-Gran

There total 19 articles about Calo-Gran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Iodine monochloride (7790-99-0) + mercury → mercuric chloride (7546-30-7,51312-24-4) + mercuric iodide (7783-30-4)

Guidance literature:

In neat (no solvent, gas phase); react. in a flowing-afterglow reactor, carrier gas Ar (flow rate 0.05 mol/min, 1.5 Torr, 50°C); not isolated; Kinetics;

DOI:10.1021/j100289a019

Reference yield:

clorine (14700-96-0,14835-24-6,15723-23-6,16547-50-5,16885-04-4,16887-00-6,16904-11-3,16904-12-4,16999-02-3,20337-89-7,20499-73-4,22537-15-1,22537-27-5,22541-73-7,22541-74-8,24203-47-2,33944-49-9,34937-26-3,37352-90-2) + mercury → mercuric chloride (7546-30-7,51312-24-4)

Guidance literature:

In neat (no solvent); rate coefficients determined as a function of pressure (200-600 Torr) and temperature (243-293 K) in N2 buffer gas and as a function of pressure(200-600 Torr) in He buffer gas at 293 K; Hg and Cl monitored by laser induced fluorescence and UV photometry; Kinetics;

DOI:10.1021/jp051354l

Reference yield:

dichloromethane (75-09-2) + mercury → mercuric chloride (7546-30-7,51312-24-4)

Guidance literature:

In neat (no solvent, gas phase); react. in a flowing-afterglow reactor, carrier gas Ar (flow rate 0.05 mol/min, 1.5 Torr, 50°C); Kinetics;

DOI:10.1021/j100289a019

upstream raw materials:

clorine

Iodine monochloride

dichloromethane

sulfur dichloride

Refernces

• 1、 Legay-Sommaire,Legay. "Photochemical insertion of Hg in the HCl bond and mercury-sensitized production of ClHCl - and KrHKr + in low-temperature matrices". . p. 40 - 46. Retrieved 2008/10/08.