N-benzyl-1-phenylethanimine

Base Information

• Chemical Name: N-benzyl-1-phenylethanimine
• CAS No.: 14428-98-9
• Molecular Formula: C15H15 N
• Molecular Weight: 209.291
• NSC Number: 168460
• Nikkaji Number: J1.022.636H,J1.022.641D,J659.509J
• Mol file: 14428-98-9.mol

Synonyms:N-benzyl-1-phenylethanimine;NSC168460;acetophenone benzylimine;Acetophenone N-benzyl imine;N-benzyl acetophenone imine;SCHEMBL164345;SCHEMBL2206812;JATCPLSBWDXCNE-UHFFFAOYSA-N;N-(1-phenylethylidene)benzylamine;(E)-Benzyl(1-phenylethylidene)amine;(e)N-benzyl-1-phenylethane-1-imine;N-benzyl-(1-phenylethylidene)-amine;N-benzyl-N-(1-phenylethylidene)amine;NSC-168460;14428-98-9;1-phenyl-N-(1-phenylethylidene)methanamine

Chemical Property of N-benzyl-1-phenylethanimine

Chemical Property:

• Vapor Pressure: 0.00152mmHg at 25°C
• Boiling Point: 305.1°C at 760 mmHg
• Flash Point: 130.3°C
• Density: 0.94g/cm³
• XLogP3: 3.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 209.120449483
• Heavy Atom Count: 16
• Complexity: 220

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=NCC1=CC=CC=C1)C2=CC=CC=C2

Technology Process of N-benzyl-1-phenylethanimine

There total 21 articles about N-benzyl-1-phenylethanimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

acetophenone (98-86-2) + benzylamine (100-46-9) → N-benzyl-N-(1-phenylethylidene)amine (14428-98-9)

Guidance literature:

With zinc(II) chloride; In toluene; for 7h; Heating;

Reference yield: 87.0%

benzaldehyde (100-52-7) + rac-methylbenzylamine (618-36-0) → (E)-1-phenyl-N-(1-phenylethylidene)methanamine (14428-98-9,98325-59-8,98359-08-1)

Guidance literature:

In ethanol; at 20 ℃; for 1h;

DOI:10.1016/0022-328X(89)85184-8

Reference yield: 85.0%

acetophenone (98-86-2) + benzylamine (100-46-9) → (E)-1-phenyl-N-(1-phenylethylidene)methanamine (14428-98-9,98325-59-8,98359-08-1)

Guidance literature:

With zinc(II) chloride; at 120 ℃; for 1h; microwave irradiation;

DOI:10.1016/j.tet.2004.05.003

upstream raw materials:

1,4-dioxane

ethanol

(R)-benzylidene-(1-phenylethyl)amine

sodium ethanolate

Downstream raw materials:

2,4,6-triphenylpyridine

dibenzylamine

N-benzyl-1-phenylethylamine

2-phenyl-4-(1-phenylethylidene)oxazol-5(4H)-one

Refernces

• 1、 Bidusenko, Ivan A.,Schmidt, Elena Yu.,Trofimov, Boris A.,Ushakov, Igor A.,Vashchenko, Alexander V.. "Base-Catalyzed [3 + 2] Cycloaddition of N-Benzyl Ketimines to Arylacetylenes Followed by Oxidation: A One-Pot Access to Polyarylated 2 H-Pyrroles via Intermediate Pyrrolines". supporting information. p. 4121 - 4126. Retrieved 2021/06/28.
• 2、 Du, Shengyu,Zhang, Chenjun,Jiang, Yuchen,Jiang, Pingping,Leng, Yan. "Au nanoparticle-immobilized L-cysteine-paired porous ionic copolymer as an efficient catalyst for additive-free oxidative coupling of alcohols and amines". . . Retrieved 2019/07/04.