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Calcium hypochlorite 7778-54-3 /manufacturer/low price/high quality/in stock
Cas No: 7778-54-3
USD $ 3.0-11.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
Calcium Hypochlorite 70% 65% (Water treatment chemicals)
Cas No: 7778-54-3
USD $ 1100.0-1180.0 / Metric Ton 1 Metric Ton 500 Metric Ton/Month Antimex Chemical Limied Contact Supplier
Calcium hypochlorite
Cas No: 7778-54-3
No Data 1 Kilogram 30 Metric Ton/Month Simagchem Corporation Contact Supplier
Calcium hypochlorite Ca(ClO)2 CAS NO.7778-54-3
Cas No: 7778-54-3
USD $ 2.0-2.0 / Gram 100 Gram 100 Metric Ton/Month Hebei yanxi chemical co.,LTD. Contact Supplier
Calcium hypochlorite
Cas No: 7778-54-3
No Data 1 Kilogram 1 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
Factory Supply Active chlorine released from calcium hypochlorite
Cas No: 7778-54-3
No Data 1 1 Ality Chemical Corporation Contact Supplier
Amadis Chemical offer CAS#7778-54-3;CAT#A851724
Cas No: 7778-54-3
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
Calcium hypochlorite
Cas No: 7778-54-3
USD $ 1.0-1.0 / Kilogram 1 Kilogram 1000 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier
TIANFU-CHEM CAS:7778-54-3 Calcium hypochlorite
Cas No: 7778-54-3
No Data 1 Gram 1 Metric Ton/Day Henan Tianfu Chemical Co., Ltd. Contact Supplier
Calcium Hypochlorite Manufacturer 7778-54-3 Disinfectant
Cas No: 7778-54-3
No Data 10 Gram 10000 Metric Ton/Month Hubei XinRunde Chemical Co., Ltd Contact Supplier

7778-54-3 Usage

Uses

Bleaching of wood pulp, linen, cotton, straw, oils, soaps, and in laundering; oxidizer in calico printing to obtain white designs on a colored ground; destroying caterpillars; disinfecting drinking water, sewage, etc.; as a decontaminant for mustard gas and similar substances.

Reactions

As strong oxidant, calcium hypochlorite may react with vigor in combination with carbon compounds, and combination with finely divided carbon particles forms an explosive mixture. Reaction with acetylene leads to creation of explosive chloroacetylenes. Contact with organic matter, oil, hydrocarbons and alcohols such as methanol or ethanol may cause a violent explosion. Reaction with nitromethane causes a delayed violent reaction. Organic sulfur compounds such as sulfides react by self-ignition and explosion. Iron oxide in metal containers catalyze oxygen-evolving decomposition of the oxidant.

Shipping

UN1748 Calcium hypochlorite, dry or Calcium hypochlorite mixtures dry with .39% available chlorine (8.8% available oxygen), Hazard Class: 5.1; Labels: 5.1- Oxidizer. UN2208 Calcium hypochlorite mixtures, dry, with .10% but not .39% available chlorine, Hazard Class: 5.1; Labels: 5.1-Oxidizer. UN2880 Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixtures, with not ,5.5% but not .16% water, Hazard Class: 5.1; Labels: 5.1-Oxidizer

Incompatibilities

A powerful oxidizer. Decomposes in heat or sunlight; becomes explosive above 100C/212F. Incompatible with strong acids; water and other forms of moisture, reducing agents; combustible materials; all other chemicals, especially acetylene, aniline and all other amines, anthracene, carbon tetrachloride, iron oxide, manganese oxide, mercaptans, diethylene glycol monomethyl ether, nitromethane, organic matter; organic sulfides, phenol, 1-propanethiol, propyl mercaptan, sulfur, turpentine, organic sulfur compounds. Attacks various metals, releasing flammable hydrogen gas.

Chemical Properties

Calcium hypochlorite is a white powder, granule, or pellets with a strong chlorine-like odor.

Preparation

Calcium hypochlorite is manufactured by two main processes, the socalled “calcium process” and the “sodium process”. These are essentially the same as described for the Mg(ClO)2 salt method given above except that a sodium hypochlorite salt is used in one

Hazard

Dangerous fire risk in contact with organic materials.

Health Hazard

Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution.

Definition

A white solid that can be regarded as a mixture of calcium chlorate(I) (calcium hypochlorite), calcium chloride, and calcium hydroxide. It is prepared on a large scale by passing a current of chlorine through a tilted cylinder down which is passed calcium hydroxide. Bleaching powder has been used for bleaching paper pulps and fabrics and for sterilizing water. Its bleaching power arises from the formation, in the presence of air containing carbon dioxide, of the oxidizing agent chloric(I) acid (hypochlorous acid, HClO): Ca(ClO)2.Ca(OH)2.CaCl2 + 2CO2 → 2CaCO3 + CaCl2 + 2HClO.

Uses

Bleaching powder is actually a mixture of calcium hypochlorite (Ca(ClO)2) and the basic chloride CaCl2, H2O with some slaked lime, Ca(OH)2. The product is generally called “bleaching powder”. It consists of a mixture of calcium chloride (CaCl2), calcium hypochlorite (Ca(OCl)2), and calcium chloride hypochlorite (CaCl(OCl)). Ca(ClO)2 is used in industrial wastewater treatment, sanitation and cleaning, epidemic prevention and household sanitation facilities, as well as for disinfection and sterilization of swimming pools, drinking water, cleaning vegetables, and sanitizing fishponds. Calcium hypochlorite has been used for bleaching of cotton, hemp, fiber, pulp and starch, disinfection of surfaces, and as a sterilant for water treatment. It has also been proposed as a solid fire extinguisher.

Industrial uses

Calcium hypochlorite Ca(OCl)2 can be found in swimming pool disinfectants, in bleaching agents, in deodorants and in fungicides.

Reactivity Profile

CALCIUM HYPOCHLORITE is a powerful oxidizing agent, particularly in the presence of water or at higher temperature as Calcium hypochlorite decomposes to release oxygen and chlorine gases. As strong oxidant Calcium hypochlorite may react with vigor in combination with carbon, especially finely divided is explosive; acetylene, leads to creation of explosive chloroacetylenes; organic matter, oil, hydrocarbons; alcohols may cause explosion, methanol, ethanol, etc.; nitromethane caused delayed violent reaction; organic sulfur compounds, sulfides tend toward ignition and sometimes explosion; with iron oxide in metal containers catalyze oxygen evolving decomposition of the oxidant. Calcium hypochlorite forms highly explosive NCl3 on contact with urea. Produces highly toxic gaseous chlorine gas when heated or on contact with acids [Sax, 9th ed., 1996, p. 1905]. Mixture of damp sulfur with hypochlorite caused a violent reaction, that ejected molten sulfur, Chem Eng. News, 1965, 46(29), 6.

References

https://pubchem.ncbi.nlm.nih.gov/compound/24504#section=Top https://en.wikipedia.org/wiki/Calcium_hypochlorite https://www.atsdr.cdc.gov/mmg/mmg.asp?id=927&tid=192

Description

Calcium hypochlorite (molecular formula: Ca (ClO)2) is a kind of inorganic compound. It appears as a white granular solid with chlorine odor. Though it is relatively stable and non-combustible, it will accelerate the burning of combustible materials. Sodium hypochlorite solid is generally not commercialized. Instead, it is highly soluble in water and can be formulated into various concentrations. The resulting sodium hypochlorite solutions appears as clear, green to yellow liquids. It has two major applications. One is sanitation. For this purpose, it is primarily used as bleaching agent or disinfectants to sanitize publish swimming pools as well as disinfect drinking water. It is also used in the disinfection of surfaces and equipment of kitchen and bathroom. Moreover, it can be used as algaecides, herbicide and laundry detergents. Another major application is in organic chemistry. It can act as a general oxidizing agent for the cleavage of glycols, keto acids to obtain fragmented aldehydes or carboxylic acid. It can also be used for the manufacture of chloroform. Calcium hypochlorite can be manufactured through the reaction between limes (Ca(OH)2) with chlorine gas to give various concentrations of products. Calcium hypochlorite is toxic. Its solution can emit toxic gases such as chlorine. Inhalation can lead to olfactory fatigue and irritation on the lung airway. It is also irritating to the skin and eye upon contact. Ingestion of it can cause vomiting and corrosive injury to the gastrointestinal tract.

Fire Hazard

These substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard.

Chemical Properties

Calcium hypochlorite, Ca(OCl)2.4H20, also known as calcium oxychloride, chlorinated lime, and bleach, is a deliquescent white powder used as a bleaching agent in the textile and pulp industries and as a disinfectant. It contains 60 to 65% available chlorine,

Physical properties

White crystalline solid; density 2.35 g/cm3; decomposes when heated to 100°C; soluble in water and alcohol (with decomposition).

Waste Disposal

Dissolve the material in water and add to a large volume of concentrated reducing agent solution, then acidify the mixture with H2SO4. When reduction is complete, soda ash is added to make the solution alkaline. The alkaline liquid is decanted from any sludge produced, neutralized, and diluted before discharge to a sewer or stream. The sludge is landfilled

General Description

Calcium hypochlorite, hydrated is a white granular solid or tablets compressed from the granules having an odor of chlorine. Calcium hypochlorite is noncombustible, but Calcium hypochlorite will accelerate the burning of combustible materials. Calcium hypochlorite is decomposed by water with evolution of chlorine gas and heat. Prolonged exposure to fire or heat may result in the vigorous decomposition of the material and rupture of the container. Material containing less than 39% available chlorine may undergo reactions as described above though Calcium hypochlorite may take longer to initiate, and the resulting reactions may not be as vigorous. Calcium hypochlorite is used for water purification, disinfectant for swimming pools, for bleaching paper and textiles, and for many other uses.
InChI:InChI=1/Ca.ClO/c;1-2/q+2;-1

7778-54-3 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (42548)  Calcium hypochlorite, tech.    7778-54-3 10g 210.0CNY Detail
Alfa Aesar (42548)  Calcium hypochlorite, tech.    7778-54-3 50g 251.0CNY Detail
Alfa Aesar (42548)  Calcium hypochlorite, tech.    7778-54-3 250g 279.0CNY Detail
Sigma-Aldrich (211389)  Calciumhypochlorite  technical grade 7778-54-3 211389-5G 469.17CNY Detail
Sigma-Aldrich (211389)  Calciumhypochlorite  technical grade 7778-54-3 211389-250G 618.93CNY Detail
Sigma-Aldrich (211389)  Calciumhypochlorite  technical grade 7778-54-3 211389-1KG 1,271.79CNY Detail

7778-54-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name Calcium Hypochlorite

1.2 Other means of identification

Product number -
Other names Hypochlorous acid calcium salt

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Disinfectant
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7778-54-3 SDS

7778-54-3Synthetic route

calcium chloride

calcium chloride

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
In water Electrolysis;
In not given Electrolysis;
In water Electrolysis;
In water Electrolysis;
calcium chloride

calcium chloride

A

calcium hypochlorite
7778-54-3

calcium hypochlorite

B

calcium hydroxide

calcium hydroxide

Conditions
ConditionsYield
In not given Electrolysis; electrolysis of neutral solutions of CaCl2 forms Ca(OH)2 on the cathode and chlorine on the anode which reacts with some Ca(OH)2 to Ca(ClO)2;;
In not given Electrolysis; electrolysis of neutral solutions of CaCl2 forms Ca(OH)2 on the cathode and chlorine on the anode which reacts with some Ca(OH)2 to Ca(ClO)2;;
calcium hydroxide

calcium hydroxide

A

calcium hypochlorite
7778-54-3

calcium hypochlorite

B

water
7732-18-5

water

C

calcium chloride

calcium chloride

Conditions
ConditionsYield
With Cl2 In neat (no solvent) effect of Cl2 on Ca(OH)2;; product mixture obtained (chloride of lime);;
With Cl2
water
7732-18-5

water

chlorine
7782-50-5

chlorine

calcium oxide

calcium oxide

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
In water byproducts: Ca(OH)2; treatment of CaO with H2O; passing in Cl2 (temp. must not exceed 40°C, cooling); cooling to 25°C when approx. 70% of theoretical amount Cl2 has been taken up; filtration through asbestos-paper, pressing; drying over NaOH in vac.;; dissolution in H2O up to saturation; filtration from insoluble residue; evapn. of the filtrate under diminished pressure until crystallisation of product; crystallisation; product contains approx. 0.5% Ca(OH)2;;
water
7732-18-5

water

chlorine
7782-50-5

chlorine

calcium hydroxide

calcium hydroxide

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
With Ca(ClO)2*3H2O In water passing of Cl2 in a mixture of Ca(OH)2 and H2O at 15°C; the CaCl2-conc. is kept constant at 30% by addition of Ca(OH)2; seeding with crystalls of Ca(ClO)2*3H2O; drying at 65°C;; product contains 75.2% Ca(ClO)2;;
With Ca(ClO)2*3H2O In water passing of Cl2 in a mixture of Ca(OH)2 and H2O at 15°C; the CaCl2-conc. is kept constant at 30% by addition of Ca(OH)2; seeding with crystalls of Ca(ClO)2*3H2O; drying at 65°C;; product contains 75.2% Ca(ClO)2;;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

calcium hydroxide

calcium hydroxide

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
In tetrachloromethane reaction of Cl2O dissolved in CCl4 with dry or suspended Ca(OH)2 at 20 - 50 °C;;
In tetrachloromethane reaction of Cl2O dissolved in CCl4 with dry or suspended Ca(OH)2 at 20 - 50 °C;;
hypochlorous anhydride
7791-21-1

hypochlorous anhydride

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
With calcium hydroxide In neat (no solvent) byproducts: H2O;
With Ca(OH)2 In neat (no solvent) byproducts: H2O;
hypochlorous anhydride
7791-21-1

hypochlorous anhydride

calcium chloride * x H2O

calcium chloride * x H2O

A

calcium hypochlorite
7778-54-3

calcium hypochlorite

B

calcium hydroxide

calcium hydroxide

Conditions
ConditionsYield
CaCl2 with various content of water of crystn. is used;;
hypochlorous anhydride
7791-21-1

hypochlorous anhydride

calcium hydroxide

calcium hydroxide

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2O;
reaction of dild. (no medium given) gasous Cl2O with dry or suspended Ca(OH)2 at 150°C;;
reaction of dild. (no medium given) gasous Cl2O with dry or suspended Ca(OH)2 at 150°C;;
chlorine
7782-50-5

chlorine

calcium oxide

calcium oxide

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
With sodium fluoride In water slaking with salt soln. and chlorinating the mixt.;;
With sodium silicate In water slaking with salt soln. and chlorinating the mixt.;;
With sodium chloride In water slaking with salt soln. and chlorinating the mixt.;;
hypochlorite
14380-61-1

hypochlorite

calcium chloride

calcium chloride

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
In water
In water reaction of alkaline hypochlorite with CaCl2;;
In water
In water reaction of alkaline hypochlorite with CaCl2;;
Ca(2+)*2ClO(1-)*2Ca(OH)2=Ca(ClO)2*2Ca(OH)2

Ca(2+)*2ClO(1-)*2Ca(OH)2=Ca(ClO)2*2Ca(OH)2

A

calcium hypochlorite
7778-54-3

calcium hypochlorite

B

calcium hydroxide

calcium hydroxide

Conditions
ConditionsYield
With water In water slow decomposition in water under pptn. of Ca(OH)2 and solving of Ca(ClO)2;;
With H2O In water slow decomposition in water under pptn. of Ca(OH)2 and solving of Ca(ClO)2;;
Ca(2+)*2ClO(1-)*2Ca(OH)2=Ca(ClO)2*2Ca(OH)2

Ca(2+)*2ClO(1-)*2Ca(OH)2=Ca(ClO)2*2Ca(OH)2

hypochloric acid
14989-30-1

hypochloric acid

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
In water neutralization of moist salt with aq. acid;; pptn.;;
In water
Ca(2+)*2ClO(1-)*2Ca(OH)2=Ca(ClO)2*2Ca(OH)2

Ca(2+)*2ClO(1-)*2Ca(OH)2=Ca(ClO)2*2Ca(OH)2

carbon dioxide
124-38-9

carbon dioxide

A

calcium hypochlorite
7778-54-3

calcium hypochlorite

B

calcium carbonate

calcium carbonate

Conditions
ConditionsYield
In water passing CO2 over salt; filtration of CaCO3 and concg. soln.;; pptn.;;
In water
chlorine
7782-50-5

chlorine

sodium hydroxide
1310-73-2

sodium hydroxide

calcium hydroxide

calcium hydroxide

A

calcium hypochlorite
7778-54-3

calcium hypochlorite

B

sodium chloride
7647-14-5

sodium chloride

Conditions
ConditionsYield
In water absorption of Cl2 from MgCl2-electrolysis in Ca(OH)2 soln. and in aq. NaOH; filtration of NaCl and mixing both solutions; concg.;; pptn.;;
calcium hypochlorite trihydrate

calcium hypochlorite trihydrate

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
In neat (no solvent) dehydration of crystalline Ca(ClO)2*3H2O in vac. at 25-50 Torr and at 45-80°C;; pure product with about 90-95% "active chlorine";;
In neat (no solvent) dehydration of crystalline Ca(ClO)2*3H2O in vac. at 25-50 Torr and at 45-80°C;; pure product with about 90-95% "active chlorine";;
wollastonite

wollastonite

chlorine
7782-50-5

chlorine

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
In not given extraction of formed hypochlorite;;
calcium aluminate

calcium aluminate

chlorine
7782-50-5

chlorine

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
In not given extraction of formed hypochlorite;;
calcium(II) ion

calcium(II) ion

hypochlorite
14380-61-1

hypochlorite

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
In water from strongly alk. soln. by evapn. at low temp.;; solid Ca(ClO)2 obtained;;
hypochlorite
14380-61-1

hypochlorite

calcium hydroxide

calcium hydroxide

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
In water
In water
tert-butylhypochlorite
507-40-4

tert-butylhypochlorite

calcium hydroxide

calcium hydroxide

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
In water
In water
hypochloric acid
14989-30-1

hypochloric acid

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
With calcium hydroxide In not given addn. of a HClO soln. to a cooled Ca(OH)2 soln. in small portions while stirring; the use of concd. solns. causes decompn.;; free of Cl(1-); only in soln.; not isolated;;
With CaCO3 In not given byproducts: CO2;
With Ca(OH)2 In not given addn. of a HClO soln. to a cooled Ca(OH)2 soln. in small portions while stirring; the use of concd. solns. causes decompn.;; free of Cl(1-); only in soln.; not isolated;;
chlorine
7782-50-5

chlorine

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
With calcium hydroxide In water passing Cl2 into aq. Ca(OH)2; the formation of Ca(ClO3)2 depends on temperature;;
With calcium hydroxide In water passing Cl2 into aq. Ca(OH)2; exceeding of the point of neutralization yields Ca(ClO3)2 and O2; the formation of Ca(ClO3)2 depends also on temperature;;
With Ca(OH)2 In water passing Cl2 into aq. Ca(OH)2; the formation of Ca(ClO3)2 depends on temperature;;
With Ca(OH)2 In water passing Cl2 into aq. Ca(OH)2; exceeding of the point of neutralization yields Ca(ClO3)2 and O2; the formation of Ca(ClO3)2 depends also on temperature;;
chlorine
7782-50-5

chlorine

calcium hydroxide

calcium hydroxide

calcium hypochlorite
7778-54-3

calcium hypochlorite

Conditions
ConditionsYield
With sodium hydroxide In water chlorination of aq. NaOH and addn. of Ca(OH)2 or chlorination of Ca(OH)2 soln. and addn. of NaOH or chlorination of Ca(OH)2 in aq. NaOH;;
With sodium hydroxide In water byproducts: NaCl; separation of Ca(ClO)2 or concg. the soln. to dryness or separation of NaCl first, then separation of Ca(ClO)2;;
With sodium hydroxide In water byproducts: NaCl; variations in process described;;
chlorine
7782-50-5

chlorine

calcium hydroxide

calcium hydroxide

A

calcium hypochlorite
7778-54-3

calcium hypochlorite

B

calcium chloride

calcium chloride

Conditions
ConditionsYield
In not given byproducts: H2O; react. is reversible;;
chlorine
7782-50-5

chlorine

calcium hydroxide

calcium hydroxide

A

calcium hypochlorite
7778-54-3

calcium hypochlorite

B

Ca(2+)*2ClO(1-)*2Ca(OH)2=Ca(ClO)2*2Ca(OH)2

Ca(2+)*2ClO(1-)*2Ca(OH)2=Ca(ClO)2*2Ca(OH)2

C

Ca(2+)*2ClO(1-)*Ca(OH)2=Ca(ClO)2*Ca(OH)2

Ca(2+)*2ClO(1-)*Ca(OH)2=Ca(ClO)2*Ca(OH)2

Conditions
ConditionsYield
In water product ratio depends on content of acitive chlorine in soln.;; product separation possible;;
In water
calcium hypochlorite
7778-54-3

calcium hypochlorite

3,3-dimethyl-1,5-dioxaspiro<5.5>undecan-9-ol
69825-15-6

3,3-dimethyl-1,5-dioxaspiro<5.5>undecan-9-ol

3,3-dimethyl-1,5-dioxaspiro[5.5]undecan-9-one
69225-59-8

3,3-dimethyl-1,5-dioxaspiro[5.5]undecan-9-one

Conditions
ConditionsYield
With sodium hydrogencarbonate In water; toluene; acetonitrile97.2%
With sodium hydrogencarbonate; sodium sulfate In water; toluene; acetonitrile
With sodium hydrogencarbonate; sodium sulfate In water; toluene; acetonitrile
In water; toluene; acetonitrile
calcium hypochlorite
7778-54-3

calcium hypochlorite

potassium hypochlorite

potassium hypochlorite

Conditions
ConditionsYield
With potassium hydroxide; potassium carbonate In water
sodium chlorite
7758-19-2

sodium chlorite

calcium hypochlorite
7778-54-3

calcium hypochlorite

sodium hydrogencarbonate
144-55-8

sodium hydrogencarbonate

sodium carbonate
497-19-8

sodium carbonate

A

carbon dioxide
124-38-9

carbon dioxide

B

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

Conditions
ConditionsYield
With sodium hydrogen sulfate In water Product distribution / selectivity; Acidic aqueous solution;
With sodium hydrogen sulfate In water Product distribution / selectivity; Acidic aqueous solution;
With sulfuric acid In water Product distribution / selectivity;
sodium hydroxide
1310-73-2

sodium hydroxide

calcium hypochlorite
7778-54-3

calcium hypochlorite

aminosulfonic acid
5329-14-6

aminosulfonic acid

A

N-monochlorosulfamic acid
17172-27-9

N-monochlorosulfamic acid

B

water
7732-18-5

water

Conditions
ConditionsYield
In water at 32.2122℃; for 0.25 - 0.5h; pH=2;
calcium hypochlorite
7778-54-3

calcium hypochlorite

aminosulfonic acid
5329-14-6

aminosulfonic acid

hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

A

N-bromosulfamic acid
791750-27-1

N-bromosulfamic acid

B

water
7732-18-5

water

C

calcium chloride

calcium chloride

Conditions
ConditionsYield
In water Product distribution / selectivity;
calcium hypochlorite
7778-54-3

calcium hypochlorite

aminosulfonic acid
5329-14-6

aminosulfonic acid

sodium bromide
7647-15-6

sodium bromide

A

N-bromosulfamic acid
791750-27-1

N-bromosulfamic acid

B

water
7732-18-5

water

C

calcium chloride

calcium chloride

Conditions
ConditionsYield
In water at 32.2122℃; for 0.25 - 0.5h; pH=2; Product distribution / selectivity;
sodium chlorite
7758-19-2

sodium chlorite

calcium hypochlorite
7778-54-3

calcium hypochlorite

sodium carbonate
497-19-8

sodium carbonate

A

carbon dioxide
124-38-9

carbon dioxide

B

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

Conditions
ConditionsYield
In water Product distribution / selectivity; Acidic aqueous solution;
sodium hydroxide
1310-73-2

sodium hydroxide

calcium hypochlorite
7778-54-3

calcium hypochlorite

N-bromosulfamic acid
791750-27-1

N-bromosulfamic acid

A

N-bromosulfamic acid sodium salt
134509-56-1

N-bromosulfamic acid sodium salt

B

water
7732-18-5

water

Conditions
ConditionsYield
In water at 32.2122℃; Product distribution / selectivity;
calcium hypochlorite
7778-54-3

calcium hypochlorite

3-methoxy-4,5-bis[(2-methoxy-ethoxy)-methoxy] benzaldehyde

3-methoxy-4,5-bis[(2-methoxy-ethoxy)-methoxy] benzaldehyde

2-chloro-3,4-bis-[(2-methoxy-ethoxy)-methoxy]-5-methoxy benzaldehyde
152355-24-3

2-chloro-3,4-bis-[(2-methoxy-ethoxy)-methoxy]-5-methoxy benzaldehyde

Conditions
ConditionsYield
In dichloromethane; water
In dichloromethane; water
calcium hypochlorite
7778-54-3

calcium hypochlorite

2-chloro-5-(2,2,2-trifluoro-1-hydroxyethyl)pyridine
150698-77-4

2-chloro-5-(2,2,2-trifluoro-1-hydroxyethyl)pyridine

1-(6-chloro-3-pyridyl)-2,2,2-trifluoroethanone
150698-72-9

1-(6-chloro-3-pyridyl)-2,2,2-trifluoroethanone

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydrogen sulfate In dichloromethane; water
calcium hypochlorite
7778-54-3

calcium hypochlorite

2-(2,2,2-trifluoroethoxy)-5-(2,2,2-trifluoro-1-hydroxyethyl)pyridine
150698-78-5

2-(2,2,2-trifluoroethoxy)-5-(2,2,2-trifluoro-1-hydroxyethyl)pyridine

2-(2,2,2-trifluoroethoxy)-5-trifluoroacetylpyridine
150698-73-0

2-(2,2,2-trifluoroethoxy)-5-trifluoroacetylpyridine

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydrogen sulfate In dichloromethane; water
calcium hypochlorite
7778-54-3

calcium hypochlorite

4'-(methylsulfonylamino)acetophenone
5317-89-5

4'-(methylsulfonylamino)acetophenone

N-(4-acetyl-2-chlorophenyl)methanesulfonamide

N-(4-acetyl-2-chlorophenyl)methanesulfonamide

Conditions
ConditionsYield
In ethyl acetate-pet; water
calcium hypochlorite
7778-54-3

calcium hypochlorite

ammonium chloride
12125-02-9

ammonium chloride

nitrogen trichloride
10025-85-1

nitrogen trichloride

Conditions
ConditionsYield
With hydrogenchloride In dichloromethane; water at 4℃; for 0.75h;
calcium hypochlorite
7778-54-3

calcium hypochlorite

1-(3-phenyl-isoxazol-5-yl)-propan-1-ol
105909-83-9

1-(3-phenyl-isoxazol-5-yl)-propan-1-ol

1-(3-phenyl-isoxazol-5-yl)-propan-1-one
104179-49-9

1-(3-phenyl-isoxazol-5-yl)-propan-1-one

Conditions
ConditionsYield
With pyridine hydrochloride In dichloromethane
calcium hypochlorite
7778-54-3

calcium hypochlorite

methylamine
74-89-5

methylamine

N-chloromethylamine
6154-14-9

N-chloromethylamine

Conditions
ConditionsYield
In nitrogen; kerosene
calcium hypochlorite
7778-54-3

calcium hypochlorite

linalool acetate
115-95-7

linalool acetate

6-chloro-7-methylene-3-methyl-1-octen-3-yl acetate
79421-89-9

6-chloro-7-methylene-3-methyl-1-octen-3-yl acetate

Conditions
ConditionsYield
With carbon dioxide; sodium hydrogencarbonate; sodium hydrogensulfite In dichloromethane; water
calcium hypochlorite
7778-54-3

calcium hypochlorite

4-methyl-benzaldehyde
104-87-0

4-methyl-benzaldehyde

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With phosphoric acid
calcium hypochlorite
7778-54-3

calcium hypochlorite

N-(4-cyanophenyl)acetamide
35704-19-9

N-(4-cyanophenyl)acetamide

N-(2-chloro-4-cyanophenyl)acetamide
53312-88-2

N-(2-chloro-4-cyanophenyl)acetamide

Conditions
ConditionsYield
With sodium chloride; acetic acid In ethanol; water
calcium hypochlorite
7778-54-3

calcium hypochlorite

aqueous potassium hypochlorite

aqueous potassium hypochlorite

2-n-Butyl-3-(4-hydroxy-benzoyl)-benzofuran
52490-15-0

2-n-Butyl-3-(4-hydroxy-benzoyl)-benzofuran

2-n-butyl-3-(3',5'-dichloro-4'-hydroxybenzoyl)benzofuran

2-n-butyl-3-(3',5'-dichloro-4'-hydroxybenzoyl)benzofuran

Conditions
ConditionsYield
With hydrogenchloride; potassium hydroxide; sodium hydroxide; potassium carbonate In methanol; water
calcium hypochlorite
7778-54-3

calcium hypochlorite

ethyl chloro[(2,4-dichlorophenyl)hydrazono]acetate
27143-12-0

ethyl chloro[(2,4-dichlorophenyl)hydrazono]acetate

Ethyl Dichloro [(2,4-dichlorophenyl)azo]acetate

Ethyl Dichloro [(2,4-dichlorophenyl)azo]acetate

Conditions
ConditionsYield
In chloroform; water; benzene
calcium hypochlorite
7778-54-3

calcium hypochlorite

chloro-(2,4,6-trichloro-phenylhydrazono)-acetic acid ethyl ester
53729-07-0

chloro-(2,4,6-trichloro-phenylhydrazono)-acetic acid ethyl ester

ethyl dichloro[(2,4,6-trichlorophenyl)azo]acetate

ethyl dichloro[(2,4,6-trichlorophenyl)azo]acetate

Conditions
ConditionsYield
In chloroform; water; benzene
calcium hypochlorite
7778-54-3

calcium hypochlorite

methyl[3,5-dichloro-4-(4-aminophenoxy)-phenyl] acetate

methyl[3,5-dichloro-4-(4-aminophenoxy)-phenyl] acetate

methyl[3,5-dichloro-4-(4-amino-3-chlorophenoxy)phenyl]acetate

methyl[3,5-dichloro-4-(4-amino-3-chlorophenoxy)phenyl]acetate

Conditions
ConditionsYield
With sodium hydroxide In water; acetic acid; acetone
calcium hypochlorite
7778-54-3

calcium hypochlorite

calcium oxide

calcium oxide

Conditions
ConditionsYield
In neat (no solvent) heating;;
calcium hypochlorite
7778-54-3

calcium hypochlorite

oxygen
80937-33-3

oxygen

Conditions
ConditionsYield
With CoO or Co(2+)-salt In water byproducts: CaCl2, H2O; addn. of CoO or a Co(2+) salt to a suspension of Ca(ClO)2 in H2O; mechanism discussed;;
In neat (no solvent) decompn. of Ca(OCl)2 at 170 - 180 °C;;
In neat (no solvent) explosion at 100 - 110°C;;
calcium hypochlorite
7778-54-3

calcium hypochlorite

chlorine
7782-50-5

chlorine

Conditions
ConditionsYield
With catalyst: Cu-Co-catalyst In neat (no solvent) heating mixture (25:1) at 60 - 120°C;;
In neat (no solvent) impured Ca(OCl)2 (data given) losses 0.1 % Cl2 at 90 °C for 3 h;;
In neat (no solvent) heating of 0.3520 g Ca(OCl)2 with 38.31 % Ca(Cl)OCl in air stream (free of CO2) for 7 h yield 0.003 g Cl2; the residue contains 30.3 % Ca(Cl)OCl;;
calcium hypochlorite
7778-54-3

calcium hypochlorite

tin(IV) oxide

tin(IV) oxide

Conditions
ConditionsYield
byproducts: O2, Cl2;
calcium hypochlorite
7778-54-3

calcium hypochlorite

phosphan
7803-51-2

phosphan

phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

Conditions
ConditionsYield
In not given oxidation of PH3 with Ca(OCl)2 soln.;;
hydrogenchloride
7647-01-0

hydrogenchloride

calcium hypochlorite
7778-54-3

calcium hypochlorite

chlorine
7782-50-5

chlorine

Conditions
ConditionsYield
In neat (no solvent)
In water Kinetics; at 25.0°C; trapped by KI;
calcium hypochlorite
7778-54-3

calcium hypochlorite

cerium(III) ion

cerium(III) ion

cerium(IV) hydroxide
12014-56-1

cerium(IV) hydroxide

Conditions
ConditionsYield
In water at pH = 5.8 - 6.1;; pptn.;;
In water
calcium hypochlorite
7778-54-3

calcium hypochlorite

lead(II) chloride

lead(II) chloride

A

chlorine
7782-50-5

chlorine

B

lead dioxide

lead dioxide

C

calcium chloride

calcium chloride

Conditions
ConditionsYield
In water
In water
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