methyl 3-((4S,5S)-1,3-di-tert-butyl-2-oxo-5-phenylimidazolidin-4-yl)propanoate

Base Information

Chemical Name:methyl 3-((4S,5S)-1,3-di-tert-butyl-2-oxo-5-phenylimidazolidin-4-yl)propanoate
CAS No.:1188292-85-4
Molecular Formula:C₂₁H₃₂N₂O₃
Molecular Weight:360.497
Hs Code.:

Synonyms:methyl 3-((4S,5S)-1,3-di-tert-butyl-2-oxo-5-phenylimidazolidin-4-yl)propanoate

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Chemical Property of methyl 3-((4S,5S)-1,3-di-tert-butyl-2-oxo-5-phenylimidazolidin-4-yl)propanoate

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Technology Process of methyl 3-((4S,5S)-1,3-di-tert-butyl-2-oxo-5-phenylimidazolidin-4-yl)propanoate

There total 10 articles about methyl 3-((4S,5S)-1,3-di-tert-butyl-2-oxo-5-phenylimidazolidin-4-yl)propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1188292-84-3
C₂₁H₃₀N₂O₃

: 1188292-85-4
methyl 3-((4S,5S)-1,3-di-tert-butyl-2-oxo-5-phenylimidazolidin-4-yl)propanoate

Guidance literature:: With palladium 10% on activated carbon; hydrogen; In methanol; at 20 ℃; for 2h;
DOI:10.1021/jo9015584

Reference yield: 75.0%

: 67-56-1
methanol

: (4S,5S)-1,3-di-tert-butyl-4-(3-hydroxypropyl)-5-phenylimidazolidin-2-one

: 1188292-85-4
methyl 3-((4S,5S)-1,3-di-tert-butyl-2-oxo-5-phenylimidazolidin-4-yl)propanoate

Guidance literature:: With dipyridinium dichromate; In N,N-dimethyl-formamide; at 20 ℃; for 24h;
DOI:10.1021/jacs.7b12628

Reference yield:

: 19656-74-7
N,N'-di-tert-butyldiaziridinone

: 1188292-85-4
methyl 3-((4S,5S)-1,3-di-tert-butyl-2-oxo-5-phenylimidazolidin-4-yl)propanoate

Guidance literature:: Multi-step reaction with 6 steps

1: copper(l) chloride; tributylphosphine; (-)-(S)-i-Pr-BTM / chloroform / 4 h / 70 °C / Inert atmosphere

2: lithium aluminium tetrahydride / tetrahydrofuran / 2 h / 0 - 20 °C

3: boron trifluoride diethyl etherate / dichloromethane / 2.08 h / -78 °C

4: tetrahydrofuran / 12 h / 0 - 60 °C

5: sodium hydroxide; dihydrogen peroxide / water / 1 h / 20 °C

6: dipyridinium dichromate / N,N-dimethyl-formamide / 24 h / 20 °C

With lithium aluminium tetrahydride; dipyridinium dichromate; tributylphosphine; (-)-(S)-i-Pr-BTM; boron trifluoride diethyl etherate; dihydrogen peroxide; copper(l) chloride; sodium hydroxide; In tetrahydrofuran; dichloromethane; chloroform; water; N,N-dimethyl-formamide;
DOI:10.1021/jacs.7b12628