3,17-dinitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine)

Base Information

• Chemical Name: 3,17-dinitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine)
• CAS No.: 443927-45-5
• Molecular Formula: C₄₇H₁₆F₁₅GaN₈O₄
• Molecular Weight: 1111.39
• Mol file: 443927-45-5.mol

Synonyms:3,17-dinitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine)

Chemical Property of 3,17-dinitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine)

Chemical Property:

Purity/Quality:

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Technology Process of 3,17-dinitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine)

There total 2 articles about 3,17-dinitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine) (322641-60-1) + sodium nitrite (7632-00-0) → 3,17-dinitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine) (443927-45-5) + 3-nitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine) (443927-44-4) + 3,17,18-trinitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine) (443927-46-6)

Guidance literature:

With tris(4-bromophenyl)aminium hexachloroantimonate; In acetonitrile; suspn. of Ga-complex, NaNO2, dry MeCN stirred for 10 min under Ar; (BrC6H4)3NSbCl6 (200 mol%) added; stirred for 1 h at room temp.; solvent evapd. to dryness; residue purified on silica gel (ethyl acetatein hexane as eluent);

DOI:10.1021/ja025851g

Reference yield: 84.0%

5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine) (322641-60-1) + sodium nitrite (7632-00-0) → 3,17-dinitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine) (443927-45-5) + 3-nitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine) (443927-44-4)

Guidance literature:

With tris(4-bromophenyl)aminium hexachloroantimonate; In acetonitrile; suspn. of Ga-complex, NaNO2, dry MeCN stirred for 10 min under Ar; (BrC6H4)3NSbCl6 (75 mol%) added; stirred for 1 h at room temp.; solvent evapd. to dryness; residue purified on silica gel (ethyl acetatein hexane as eluent); recrystd. (CH2Cl2/hexane);

DOI:10.1021/ja025851g

upstream raw materials:

5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine)

sodium nitrite