[(4R,5R)-5-[(4R,5R)-5-(benzoyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl benzoate

Base Information

• Chemical Name: [(4R,5R)-5-[(4R,5R)-5-(benzoyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl benzoate
• CAS No.: 111766-71-3
• Molecular Formula: C₂₆H₃₀O₈
• Molecular Weight: 470.519

Synonyms:[(4R,5R)-5-[(4R,5R)-5-(benzoyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl benzoate

Chemical Property of [(4R,5R)-5-[(4R,5R)-5-(benzoyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl benzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(4R,5R)-5-[(4R,5R)-5-(benzoyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl benzoate

There total 12 articles about [(4R,5R)-5-[(4R,5R)-5-(benzoyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

1,6-di-O-benzoyl-D-mannitol (7226-27-9) + 2,2-dimethoxy-propane (77-76-9) → [(4R,5R)-5-[(4R,5R)-5-(benzoyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl benzoate (111766-71-3) + [(4R,4aR,8R,8aR)-4-(benzoyloxymethyl)-2,2,6,6-tetramethyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-8-yl]methyl benzoate (111651-31-1)

Guidance literature:

With toluene-4-sulfonic acid; at 28 ℃; for 10h;

Reference yield: 17.0%

1,6-di-O-benzoyl-D-mannitol (7226-27-9) + 2,2-dimethoxy-propane (77-76-9) → 1,6-di-O-benzoyl-3,4-di-O-isopropylidene-D-mannitol (51432-64-5) + [(4R,5R)-5-[(4R,5R)-5-(benzoyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl benzoate (111766-71-3) + [(4R,4aR,8R,8aR)-4-(benzoyloxymethyl)-2,2,6,6-tetramethyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-8-yl]methyl benzoate (111651-31-1)

Guidance literature:

With toluene-4-sulfonic acid; at 80 ℃; for 1h;

DOI:10.1016/0008-6215(88)84059-X

Reference yield:

benzoyl chloride (98-88-4) + 2,3;5,6-di-O-isopropylidene-1,4-dihydroxy-D-galactitol (3969-61-7,20581-94-6,28910-18-1,71771-89-6,73209-94-6,109008-02-8,120442-06-0,127707-49-7) → O1,O6-dibenzoyl-O2,O3;O4,O5-diisopropylidene-galactitol (96075-43-3,111766-71-3)

Guidance literature:

With quinoline;

DOI:10.1039/jr9560000636 DOI:10.1021/ja01878a049

upstream raw materials:

pyridine

benzoyl chloride

2,3;5,6-di-O-isopropylidene-1,4-dihydroxy-D-galactitol

quinoline

Downstream raw materials:

R,R-4,4'-bi-(2,2-dimethyl-5-p-tolylsulphonylmethyldioxolanyl)

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 111766-71-3 [(4R,5R)-5-[(4R,5R)-5-(benzoyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl benzoate

Send

Send

Metric Ton KG G Pound L ML

Send

Send