METHYL 2-HYDROXY-1-NAPHTHOATE

Base Information

• Chemical Name: METHYL 2-HYDROXY-1-NAPHTHOATE
• CAS No.: 947-65-9
• Molecular Formula: C12H10O3
• Molecular Weight: 202.21
• Hs Code.: 2918290000
• Mol file: 947-65-9.mol

Synonyms:METHYL-2-HYDROXY-1-NAPHTHALENE CARBOXYLATE;METHYL 2-HYDROXY-1-NAPHTHOATE;2-HYDROXY-1-NAPHTHOIC ACID METHYL ESTER;RARECHEM AL BF 0092;2-Hydroxy-1-naphthoate methyl ester

Chemical Property of METHYL 2-HYDROXY-1-NAPHTHOATE

Chemical Property:

• Vapor Pressure: 8.59E-05mmHg at 25°C
• Melting Point: 79-81°C
• Boiling Point: 330.5°Cat760mmHg
• PKA: 8.02±0.50(Predicted)
• Flash Point: 142.5°C
• PSA: 46.53000
• Density: 1.264g/cm³
• LogP: 2.33200
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

Methyl-2-hydroxy-1-naphthalene carboxylate >97% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHYL 2-HYDROXY-1-NAPHTHOATE

There total 21 articles about METHYL 2-HYDROXY-1-NAPHTHOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

methyl iodide (74-88-4) + 2-hydroxy-1-naphthalenecarboxylic acid (2283-08-1) → methyl 2-hydroxy-1-naphthoate (947-65-9)

Guidance literature:

With potassium hydrogencarbonate; In N,N-dimethyl-formamide; at 40 ℃;

DOI:10.1081/SCC-200046532

Reference yield: 94.0%

sodium methylate (124-41-4) + N-ethylnaphth<1,2-d>isoxazolium fluoroborate → methyl 2-hydroxy-1-naphthoate (947-65-9)

Guidance literature:

In methanol;

Reference yield: 90.0%

methanol (67-56-1) + 2-hydroxy-1-naphthalenecarboxylic acid (2283-08-1) → methyl 2-hydroxy-1-naphthoate (947-65-9)

Guidance literature:

With pyridine; toluene-4-sulfonic acid; dicyclohexyl-carbodiimide; at 20 ℃; for 24h;

DOI:10.1055/s-2004-829158

upstream raw materials:

diazomethane

2-hydroxy-1-naphthalenecarboxylic acid

methanol

methyl 3-oxo-5-phenylpentanoate

Downstream raw materials:

2-(N-[2]naphthyl-benzimidoyloxy)-[1]naphthoic acid methyl ester

<1-(2-hydroxynaphthyl)>diphenylmethanol

β-naphthol

1-carbomethoxy-2-(trifluoromethylsulfonyloxy)naphthalene