Tetramethylammonium formate

Base Information

• Chemical Name: Tetramethylammonium formate
• CAS No.: 59138-84-0
• Molecular Formula: C5H13NO2
• Molecular Weight: 119.164
• European Community (EC) Number: 261-622-8
• NSC Number: 118059
• DSSTox Substance ID: DTXSID7069312
• Mol file: 59138-84-0.mol

Synonyms:Tetramethylammonium formate;59138-84-0;Fibrogenina;Forgenin;Tonoformina;tetramethylazanium;formate;Methanaminium, N,N,N-trimethyl-, formate;EINECS 261-622-8;N,N,N-Trimethylmethanaminium formate;AMMONIUM, TETRAMETHYL-, FORMATE;Methanaminium, N,N,N-trimethyl-, formate (1:1);Tetramethylammoniumformiat;C4H12N.CHO2;Ammonium, formate;SCHEMBL36852;DTXSID7069312;C4-H12-N.C-H-O2;WLN: 1K1&1&1 &VHO;MFCD00054402;NSC118059;AKOS025295501;Methanaminium,N,N-trimethyl-, formate;NSC 118059;NSC-118059;LS-19065;Formic acid tetramethylammonium salt solution

Chemical Property of Tetramethylammonium formate

Chemical Property:

• Refractive Index: n20/D 1.364
• Boiling Point: 102 °C
• PSA: 40.13000
• Density: 1.02 g/mL at 25 °C
• LogP: -0.67560
• Water Solubility.: Fully miscible in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 119.094628657
• Heavy Atom Count: 8
• Complexity: 26.6

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tetramethylammonium formate solution 30wt. % in H ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[N+](C)(C)C.C(=O)[O-]
• Uses: Tetramethylammonium formate may provide the lowest temperature sensitivity, additionally reducing corrosion of stainless-steel flow system by chloride-induced depassivation

Technology Process of Tetramethylammonium formate

There total 3 articles about Tetramethylammonium formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

formic acid (64-18-6) + tetramethyl ammoniumhydroxide (75-59-2,104422-11-9,123626-97-1,154636-59-6,195460-17-4,78017-87-5,93615-68-0,129654-61-1) → tetramethylammonium formiate (59138-84-0)

Guidance literature:

In methanol; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1021/acs.orglett.5b00692

Reference yield:

formic acid (64-18-6) + trimethylamine (75-50-3) → tetramethylammonium formiate (59138-84-0)

Guidance literature:

With methanol; at 140 ℃;

Reference yield:

→ tetramethylammonium formiate (59138-84-0)

Guidance literature:

upstream raw materials:

formic acid

trimethylamine

tetramethyl ammoniumhydroxide

Downstream raw materials:

2-methyl-2-(2-phenylethyl)but-3-enoic acid

Refernces

• 1、 -. "Process for the hydrogenation of nitrated paraffins using a palladium on carbon catalyst characterized by a low ash and a low halide content". . . Retrieved 2008/06/13.