N-methyl-N-[(E)-1-phenylethylideneamino]aniline

Base Information

Chemical Name:N-methyl-N-[(E)-1-phenylethylideneamino]aniline
CAS No.:3741-87-5
Molecular Formula:C₁₅H₁₆N₂
Molecular Weight:224.305
Hs Code.:
NSC Number:509294
DSSTox Substance ID:DTXSID50429843
Mol file:3741-87-5.mol

Synonyms:NSC509294;3741-87-5;DTXSID50429843;NSC-509294

Suppliers and Price of N-methyl-N-[(E)-1-phenylethylideneamino]aniline

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of N-methyl-N-[(E)-1-phenylethylideneamino]aniline

Chemical Property:

Vapor Pressure:0.000131mmHg at 25°C
Boiling Point:334.1°Cat760mmHg
Flash Point:155.9°C
Density:0.97g/cm³
XLogP3:3.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:224.131348519
Heavy Atom Count:17
Complexity:248

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=NN(C)C1=CC=CC=C1)C2=CC=CC=C2
Isomeric SMILES:C/C(=N\N(C)C1=CC=CC=C1)/C2=CC=CC=C2

Technology Process of N-methyl-N-[(E)-1-phenylethylideneamino]aniline

There total 8 articles about N-methyl-N-[(E)-1-phenylethylideneamino]aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 618-40-6
1-Methyl-1-phenylhydrazine

: 98-86-2
acetophenone

: 3741-87-5,15754-37-7
acetophenone N-methyl-N-phenylhydrazone

Guidance literature:: In ethanol; at 95 ℃; for 0.166667h;
DOI:10.1016/0223-5234(87)90010-9

Reference yield: 69.0%

: 618-40-6
1-Methyl-1-phenylhydrazine

: 536-74-3
phenylacetylene

: 67134-48-9
1-methyl-1-phenyl-2-(2-phenylethylidene)hydrazine

: 3741-87-5,15754-37-7
acetophenone N-methyl-N-phenylhydrazone

Guidance literature:: With bis(N-2,6-diisoprpylphenylbenzamidato)bis(dimethylamido)titanium (IV); In benzene-d6; at 65 ℃; for 4h; Overall yield = 81 %; regioselective reaction; Inert atmosphere; Sealed tube;
DOI:10.1021/jo402668q

Reference yield:

: 583-11-9,59130-82-4
N-(1-phenylethylidene)phenylhydrazine

: 74-88-4
methyl iodide

: 3741-87-5,15754-37-7
acetophenone N-methyl-N-phenylhydrazone

Guidance literature:: N-(1-phenylethylidene)phenylhydrazine; With sodium hydride; In tetrahydrofuran; at 0 ℃; for 0.25h;

methyl iodide; In tetrahydrofuran; at 0 ℃; for 5h; Reflux;
DOI:10.1002/anie.201204339