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563-63-3

Basic Information
CAS No.: 563-63-3
Name: Silver acetate
Article Data: 42
Molecular Structure:
Molecular Structure of 563-63-3 (Silver acetate)
Formula: C2H3AgO2
Molecular Weight: 166.913
Synonyms: Aceticacid, silver(1+) salt (8CI,9CI);Silver acetate (6CI,7CI);Silver acetate(AgOAc);Silver monoacetate;Silver(1+) acetate;Silver(I) acetate;
EINECS: 209-254-9
Density: 3.25 g/cm3
Melting Point: decomposes [STR93]
Boiling Point: 117.1°C at 760 mmHg
Flash Point: 40°C
Solubility: 10.2 g/L (20 °C) in water
Appearance: Off-white/brown crystalline powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-36/37/39
Transport Information: UN 1759
PSA: 26.30000
LogP: 0.01380
Synthetic route
64-19-7

acetic acid

20667-12-3

silver(l) oxide

563-63-3

silver(I) acetate

Conditions
ConditionsYield
at 50℃; for 0.0833333h;99%
In acetic acid react. of freshly prepared Ag2O (by electrolysis) with stoichiometric amounts of concd. acid, evapn. until begin of crystn., removal of remaining H2O under diminished pressure; apparatus described;;
In acetic acid crystn. on evapn. of the soln.;;
In acetic acid react. of freshly prepared Ag2O (by electrolysis) with stoichiometric amounts of concd. acid, evapn. until begin of crystn., removal of remaining H2O under diminished pressure; apparatus described;;
127-09-3

sodium acetate

silver nitrate

563-63-3

silver(I) acetate

Conditions
ConditionsYield
With acetic acid In water at 23℃;91%
With acetic acid In water addn. of satd. aq. soln. of sodium acetate to satd. aq. soln. of AgNO3 contg. few drops of acetic acid in the dark; filtration, washing the residue with water, methanol, hexane, drying in vac.;90%
In water soln. of AgNO3 in water was added to soln. of NaCH3CO2 in water; filtered in air, washed with water, EtOH, Et2O, dried in vacuo; elem. anal.;64%
1308661-15-5

Pd[(μ-O2CMe)2Ag(HO2CMe)2]2

5144-89-8

1,10-phenanthroline hydrate

35679-81-3

(1,10-phenanthroline)-palladium(II) acetate

B

563-63-3

silver(I) acetate

Conditions
ConditionsYield
In benzene benzene soln. of ligand added with stirring to benzene soln. of Pd compd. (1:1 molar ratio), mixt. stirred at room temp. for 30 min; ppt. filtered off, concd., pptd. (heptane), dried, elem. anal.;A 75%
B n/a
1308661-15-5

Pd[(μ-O2CMe)2Ag(HO2CMe)2]2

75-65-0

tert-butyl alcohol

A

palladium(II) pivalate

B

563-63-3

silver(I) acetate

Conditions
ConditionsYield
In benzene benzene soln. of ligand added with stirring to benzene soln. of Pd compd. (3:1 molar ratio), mixt. stirred at room temp. for 1.5 h; ppt. filtered off, concd., crystd., dried, elem. anal.;A 70%
B n/a
53897-55-5

2,4,6-trimethyl-[1,3,5]dioxathiane

moist silver oxide

moist silver oxide

A

563-63-3

silver(I) acetate

B

silver formate

silver formate

C

silver sulfide

silver sulfide

Conditions
ConditionsYield
bei der Oxydation;
849585-22-4

LACTIC ACID

Ag2O

Ag2O

A

124-38-9

carbon dioxide

B

563-63-3

silver(I) acetate

Conditions
ConditionsYield
at 100℃;
141-53-7

sodium formate

108-24-7

acetic anhydride

563-63-3

silver(I) acetate

Conditions
ConditionsYield
In acetic anhydride boiling, pptn.;; recrystn. from glacial acetic acid;;

diammine silver(I) acetate

563-63-3

silver(I) acetate

Conditions
ConditionsYield
With aldehyde In water
With aldehyde In water

diammine silver(I) acetate

A

7664-41-7

ammonia

B

563-63-3

silver(I) acetate

Conditions
ConditionsYield
In water in the air;
In water in the air;

silver perchlorate

563-63-3

silver(I) acetate

Conditions
ConditionsYield
With trimethylamine acetate triacetatesolvate In not given addition of AgClO4 to a solution of the triacetatesolvate of trimethylamine acetate;;
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    Silver acetate

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  • Silver Acetate

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    Silver Acetate

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    Silver acetate

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  • Aceticacid, silver(1+) salt (1:1)

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    563-63-3

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  • Silver acetate, anhydrous

  • Casno:

    563-63-3

    Silver acetate, anhydrous

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Consensus Reports

Reported in EPA TSCA Inventory.

Standards and Recommendations

ACGIH TLV: TWA 0.01 mg(Ag)/m3

Specification

The Silver(I) acetate, with the CAS registry number 563-63-3, is also known as Acetic acid, silver(1+) salt. It belongs to the product category of Organic-metal Salt. Its EINECS registry number is 209-254-9. This chemical's molecular formula is C2H3AgO2 and molecular weight is 166.91222. Its IUPAC name is called silver acetate.

Physical properties of Silver(I) acetate: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 2; (3)Rotatable Bond Count: 0; (4)Exact Mass: 165.918397; (5)MonoIsotopic Mass: 165.918397; (6)Topological Polar Surface Area: 40.1; (7)Heavy Atom Count: 5; (8)Formal Charge: 0; (9)Complexity: 25.5; (10)Covalently-Bonded Unit Count: 2.

Preparation: this chemical can be prepared by AgO and CH3COOH.

Uses of Silver(I) acetate: It can be used as a pesticide. It also produces a repulsive taste when combined with cigarette smoke, so it is used in chewing gum and lozenges to aid the cessation of smoking.

When you are using this chemical, please be cautious about it as the following:
This chemical may cause inflammation to the skin or other mucous membranes. It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing, gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: CC(=O)[O-].[Ag+]
(2)InChI: InChI=1S/C2H4O2.Ag/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1
(3)InChIKey: CQLFBEKRDQMJLZ-UHFFFAOYSA-M

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 34mg/kg (34mg/kg) BEHAVIORAL: EXCITEMENT

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Drug and Chemical Toxicology. Vol. 6, Pg. 267, 1983.